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4-Amino-3-(p-tolyloxymethyl)-1H-1,2,4-triazole-5(4H)-thione
In the title triazole compound, C(10)H(12)N(4)OS, the triazole ring is essentially planar [maximum deviation = 0.009 (1) Å] and forms a dihedral angle of 5.78 (4)° with the benzene ring. In the crystal structure, molecules are linked into dimers by centrosymmetric N—H⋯S interactions. These dimers...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977210/ https://www.ncbi.nlm.nih.gov/pubmed/21583604 http://dx.doi.org/10.1107/S1600536809027664 |
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author | Fun, Hoong-Kun Goh, Jia Hao Vijesh, A. M. Padaki, Mahesh Isloor, Arun M. |
author_facet | Fun, Hoong-Kun Goh, Jia Hao Vijesh, A. M. Padaki, Mahesh Isloor, Arun M. |
author_sort | Fun, Hoong-Kun |
collection | PubMed |
description | In the title triazole compound, C(10)H(12)N(4)OS, the triazole ring is essentially planar [maximum deviation = 0.009 (1) Å] and forms a dihedral angle of 5.78 (4)° with the benzene ring. In the crystal structure, molecules are linked into dimers by centrosymmetric N—H⋯S interactions. These dimers are linked into two-molecule-wide tapes by N—H⋯N and S⋯S [3.2634 (3) Å] interactions. In addition, they are further interconnected by weak N—H⋯S interactions into sheets parallel to the ab plane. The crystal structure is further stabilized by weak intermolecular C—H⋯π interactions. |
format | Text |
id | pubmed-2977210 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29772102010-12-30 4-Amino-3-(p-tolyloxymethyl)-1H-1,2,4-triazole-5(4H)-thione Fun, Hoong-Kun Goh, Jia Hao Vijesh, A. M. Padaki, Mahesh Isloor, Arun M. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title triazole compound, C(10)H(12)N(4)OS, the triazole ring is essentially planar [maximum deviation = 0.009 (1) Å] and forms a dihedral angle of 5.78 (4)° with the benzene ring. In the crystal structure, molecules are linked into dimers by centrosymmetric N—H⋯S interactions. These dimers are linked into two-molecule-wide tapes by N—H⋯N and S⋯S [3.2634 (3) Å] interactions. In addition, they are further interconnected by weak N—H⋯S interactions into sheets parallel to the ab plane. The crystal structure is further stabilized by weak intermolecular C—H⋯π interactions. International Union of Crystallography 2009-07-18 /pmc/articles/PMC2977210/ /pubmed/21583604 http://dx.doi.org/10.1107/S1600536809027664 Text en © Fun et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Fun, Hoong-Kun Goh, Jia Hao Vijesh, A. M. Padaki, Mahesh Isloor, Arun M. 4-Amino-3-(p-tolyloxymethyl)-1H-1,2,4-triazole-5(4H)-thione |
title | 4-Amino-3-(p-tolyloxymethyl)-1H-1,2,4-triazole-5(4H)-thione |
title_full | 4-Amino-3-(p-tolyloxymethyl)-1H-1,2,4-triazole-5(4H)-thione |
title_fullStr | 4-Amino-3-(p-tolyloxymethyl)-1H-1,2,4-triazole-5(4H)-thione |
title_full_unstemmed | 4-Amino-3-(p-tolyloxymethyl)-1H-1,2,4-triazole-5(4H)-thione |
title_short | 4-Amino-3-(p-tolyloxymethyl)-1H-1,2,4-triazole-5(4H)-thione |
title_sort | 4-amino-3-(p-tolyloxymethyl)-1h-1,2,4-triazole-5(4h)-thione |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977210/ https://www.ncbi.nlm.nih.gov/pubmed/21583604 http://dx.doi.org/10.1107/S1600536809027664 |
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