Poly[hemi-μ-aqua-[μ-2-(2-bromobenzenesulfonamido)benzoato]sodium(I)]

The asymmetric unit of the title compound, [Na(C(13)H(9)BrNO(4)S)(H(2)O)(0.5)](n), contains two Na(+) cations, two substituted benzoate anions and one water molecule of crystallization. The Na(+) cations are coordinated in an octa­hedral geometry by two carboxyl­ate O atoms, two sulfonyl O atoms and...

Descripción completa

Detalles Bibliográficos
Autores principales: Khan, Islam Ullah, Arshad, Muhammad Nadeem, Akkurt, Mehmet, Mustafa, Ghulam, Shafiq, Muhammad
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977212/
https://www.ncbi.nlm.nih.gov/pubmed/21583425
http://dx.doi.org/10.1107/S1600536809028505
_version_ 1782191054094598144
author Khan, Islam Ullah
Arshad, Muhammad Nadeem
Akkurt, Mehmet
Mustafa, Ghulam
Shafiq, Muhammad
author_facet Khan, Islam Ullah
Arshad, Muhammad Nadeem
Akkurt, Mehmet
Mustafa, Ghulam
Shafiq, Muhammad
author_sort Khan, Islam Ullah
collection PubMed
description The asymmetric unit of the title compound, [Na(C(13)H(9)BrNO(4)S)(H(2)O)(0.5)](n), contains two Na(+) cations, two substituted benzoate anions and one water molecule of crystallization. The Na(+) cations are coordinated in an octa­hedral geometry by two carboxyl­ate O atoms, two sulfonyl O atoms and two water O atoms. The latter two ligands occupy trans positions. The polymeric network structure of the title complex is characterized by a layered assembly parallel to (001) and is further consolidated by N—H⋯O, O—H⋯O and C—H⋯O hydrogen-bonding inter­actions.
format Text
id pubmed-2977212
institution National Center for Biotechnology Information
language English
publishDate 2009
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29772122010-12-30 Poly[hemi-μ-aqua-[μ-2-(2-bromobenzenesulfonamido)benzoato]sodium(I)] Khan, Islam Ullah Arshad, Muhammad Nadeem Akkurt, Mehmet Mustafa, Ghulam Shafiq, Muhammad Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, [Na(C(13)H(9)BrNO(4)S)(H(2)O)(0.5)](n), contains two Na(+) cations, two substituted benzoate anions and one water molecule of crystallization. The Na(+) cations are coordinated in an octa­hedral geometry by two carboxyl­ate O atoms, two sulfonyl O atoms and two water O atoms. The latter two ligands occupy trans positions. The polymeric network structure of the title complex is characterized by a layered assembly parallel to (001) and is further consolidated by N—H⋯O, O—H⋯O and C—H⋯O hydrogen-bonding inter­actions. International Union of Crystallography 2009-07-25 /pmc/articles/PMC2977212/ /pubmed/21583425 http://dx.doi.org/10.1107/S1600536809028505 Text en © Khan et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Khan, Islam Ullah
Arshad, Muhammad Nadeem
Akkurt, Mehmet
Mustafa, Ghulam
Shafiq, Muhammad
Poly[hemi-μ-aqua-[μ-2-(2-bromobenzenesulfonamido)benzoato]sodium(I)]
title Poly[hemi-μ-aqua-[μ-2-(2-bromobenzenesulfonamido)benzoato]sodium(I)]
title_full Poly[hemi-μ-aqua-[μ-2-(2-bromobenzenesulfonamido)benzoato]sodium(I)]
title_fullStr Poly[hemi-μ-aqua-[μ-2-(2-bromobenzenesulfonamido)benzoato]sodium(I)]
title_full_unstemmed Poly[hemi-μ-aqua-[μ-2-(2-bromobenzenesulfonamido)benzoato]sodium(I)]
title_short Poly[hemi-μ-aqua-[μ-2-(2-bromobenzenesulfonamido)benzoato]sodium(I)]
title_sort poly[hemi-μ-aqua-[μ-2-(2-bromobenzenesulfonamido)benzoato]sodium(i)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977212/
https://www.ncbi.nlm.nih.gov/pubmed/21583425
http://dx.doi.org/10.1107/S1600536809028505
work_keys_str_mv AT khanislamullah polyhemimaquam22bromobenzenesulfonamidobenzoatosodiumi
AT arshadmuhammadnadeem polyhemimaquam22bromobenzenesulfonamidobenzoatosodiumi
AT akkurtmehmet polyhemimaquam22bromobenzenesulfonamidobenzoatosodiumi
AT mustafaghulam polyhemimaquam22bromobenzenesulfonamidobenzoatosodiumi
AT shafiqmuhammad polyhemimaquam22bromobenzenesulfonamidobenzoatosodiumi

Ejemplares similares