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3-[(E)-(4-Ethyl­phen­yl)imino­meth­yl]benzene-1,2-diol

The title compound, C(15)H(15)NO(2), adopts the enol–imine tautomeric form. The dihedral angle between the two benzene rings is 48.1 (1)°. Intra­molecular O—H⋯N and O—H⋯O hydrogen bonds generate S(6) and S(5) ring motifs, respectively. In the crystal, mol­ecules are linked into centrosymmetric R (2)...

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Detalles Bibliográficos
Autores principales: Keleşoğlu, Zeynep, Büyükgüngör, Orhan, Albayrak, Çiğdem, Odabaşoğlu, Mustafa
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977215/
https://www.ncbi.nlm.nih.gov/pubmed/21583717
http://dx.doi.org/10.1107/S1600536809029924
Descripción
Sumario:The title compound, C(15)H(15)NO(2), adopts the enol–imine tautomeric form. The dihedral angle between the two benzene rings is 48.1 (1)°. Intra­molecular O—H⋯N and O—H⋯O hydrogen bonds generate S(6) and S(5) ring motifs, respectively. In the crystal, mol­ecules are linked into centrosymmetric R (2) (2)(10) dimers via pairs of O—H⋯O hydrogen bonds and the dimers may interact through very weak by π–π inter­actions [centroid–centroid distance = 4.150 (1) Å]. The ethyl group is disordered over two orientations, with occupancies of 0.587 (11) and 0.413 (11).