3-[(E)-(4-Ethyl­phen­yl)imino­meth­yl]benzene-1,2-diol

The title compound, C(15)H(15)NO(2), adopts the enol–imine tautomeric form. The dihedral angle between the two benzene rings is 48.1 (1)°. Intra­molecular O—H⋯N and O—H⋯O hydrogen bonds generate S(6) and S(5) ring motifs, respectively. In the crystal, mol­ecules are linked into centrosymmetric R (2)...

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Autores principales: Keleşoğlu, Zeynep, Büyükgüngör, Orhan, Albayrak, Çiğdem, Odabaşoğlu, Mustafa
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977215/
https://www.ncbi.nlm.nih.gov/pubmed/21583717
http://dx.doi.org/10.1107/S1600536809029924
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author Keleşoğlu, Zeynep
Büyükgüngör, Orhan
Albayrak, Çiğdem
Odabaşoğlu, Mustafa
author_facet Keleşoğlu, Zeynep
Büyükgüngör, Orhan
Albayrak, Çiğdem
Odabaşoğlu, Mustafa
author_sort Keleşoğlu, Zeynep
collection PubMed
description The title compound, C(15)H(15)NO(2), adopts the enol–imine tautomeric form. The dihedral angle between the two benzene rings is 48.1 (1)°. Intra­molecular O—H⋯N and O—H⋯O hydrogen bonds generate S(6) and S(5) ring motifs, respectively. In the crystal, mol­ecules are linked into centrosymmetric R (2) (2)(10) dimers via pairs of O—H⋯O hydrogen bonds and the dimers may interact through very weak by π–π inter­actions [centroid–centroid distance = 4.150 (1) Å]. The ethyl group is disordered over two orientations, with occupancies of 0.587 (11) and 0.413 (11).
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spelling pubmed-29772152010-12-30 3-[(E)-(4-Ethyl­phen­yl)imino­meth­yl]benzene-1,2-diol Keleşoğlu, Zeynep Büyükgüngör, Orhan Albayrak, Çiğdem Odabaşoğlu, Mustafa Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(15)H(15)NO(2), adopts the enol–imine tautomeric form. The dihedral angle between the two benzene rings is 48.1 (1)°. Intra­molecular O—H⋯N and O—H⋯O hydrogen bonds generate S(6) and S(5) ring motifs, respectively. In the crystal, mol­ecules are linked into centrosymmetric R (2) (2)(10) dimers via pairs of O—H⋯O hydrogen bonds and the dimers may interact through very weak by π–π inter­actions [centroid–centroid distance = 4.150 (1) Å]. The ethyl group is disordered over two orientations, with occupancies of 0.587 (11) and 0.413 (11). International Union of Crystallography 2009-07-31 /pmc/articles/PMC2977215/ /pubmed/21583717 http://dx.doi.org/10.1107/S1600536809029924 Text en © Keleşoğlu et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Keleşoğlu, Zeynep
Büyükgüngör, Orhan
Albayrak, Çiğdem
Odabaşoğlu, Mustafa
3-[(E)-(4-Ethyl­phen­yl)imino­meth­yl]benzene-1,2-diol
title 3-[(E)-(4-Ethyl­phen­yl)imino­meth­yl]benzene-1,2-diol
title_full 3-[(E)-(4-Ethyl­phen­yl)imino­meth­yl]benzene-1,2-diol
title_fullStr 3-[(E)-(4-Ethyl­phen­yl)imino­meth­yl]benzene-1,2-diol
title_full_unstemmed 3-[(E)-(4-Ethyl­phen­yl)imino­meth­yl]benzene-1,2-diol
title_short 3-[(E)-(4-Ethyl­phen­yl)imino­meth­yl]benzene-1,2-diol
title_sort 3-[(e)-(4-ethyl­phen­yl)imino­meth­yl]benzene-1,2-diol
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977215/
https://www.ncbi.nlm.nih.gov/pubmed/21583717
http://dx.doi.org/10.1107/S1600536809029924
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