(E)-3-Bromo-N′-(4-hydr­oxy-3-nitro­benzyl­idene)benzohydrazide

The title compound, C(14)H(10)BrN(3)O(4), was synthesized by the reaction of 4-hydr­oxy-3-nitro­benzaldehyde with an equimolar quantity of 3-bromo­benzohydrazide in methanol. The mol­ecule displays an E configuration about the C=N bond. The dihedral angle between the two benzene rings is 4.6 (2)°. T...

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Detalles Bibliográficos
Autores principales: Cao, Guo-Biao, Wang, Xiao-Ya
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977221/
https://www.ncbi.nlm.nih.gov/pubmed/21583442
http://dx.doi.org/10.1107/S1600536809024131
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author Cao, Guo-Biao
Wang, Xiao-Ya
author_facet Cao, Guo-Biao
Wang, Xiao-Ya
author_sort Cao, Guo-Biao
collection PubMed
description The title compound, C(14)H(10)BrN(3)O(4), was synthesized by the reaction of 4-hydr­oxy-3-nitro­benzaldehyde with an equimolar quantity of 3-bromo­benzohydrazide in methanol. The mol­ecule displays an E configuration about the C=N bond. The dihedral angle between the two benzene rings is 4.6 (2)°. The nitro group is almost coplanar with the attached benzene ring [dihedral angle = 4.7 (2)°]. In the crystal structure, mol­ecules are linked into sheets parallel to (100) by inter­molecular N—H⋯O, O—H⋯N and O—H⋯O hydrogen bonds.
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spelling pubmed-29772212010-12-30 (E)-3-Bromo-N′-(4-hydr­oxy-3-nitro­benzyl­idene)benzohydrazide Cao, Guo-Biao Wang, Xiao-Ya Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(14)H(10)BrN(3)O(4), was synthesized by the reaction of 4-hydr­oxy-3-nitro­benzaldehyde with an equimolar quantity of 3-bromo­benzohydrazide in methanol. The mol­ecule displays an E configuration about the C=N bond. The dihedral angle between the two benzene rings is 4.6 (2)°. The nitro group is almost coplanar with the attached benzene ring [dihedral angle = 4.7 (2)°]. In the crystal structure, mol­ecules are linked into sheets parallel to (100) by inter­molecular N—H⋯O, O—H⋯N and O—H⋯O hydrogen bonds. International Union of Crystallography 2009-07-01 /pmc/articles/PMC2977221/ /pubmed/21583442 http://dx.doi.org/10.1107/S1600536809024131 Text en © Cao and Wang 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Cao, Guo-Biao
Wang, Xiao-Ya
(E)-3-Bromo-N′-(4-hydr­oxy-3-nitro­benzyl­idene)benzohydrazide
title (E)-3-Bromo-N′-(4-hydr­oxy-3-nitro­benzyl­idene)benzohydrazide
title_full (E)-3-Bromo-N′-(4-hydr­oxy-3-nitro­benzyl­idene)benzohydrazide
title_fullStr (E)-3-Bromo-N′-(4-hydr­oxy-3-nitro­benzyl­idene)benzohydrazide
title_full_unstemmed (E)-3-Bromo-N′-(4-hydr­oxy-3-nitro­benzyl­idene)benzohydrazide
title_short (E)-3-Bromo-N′-(4-hydr­oxy-3-nitro­benzyl­idene)benzohydrazide
title_sort (e)-3-bromo-n′-(4-hydr­oxy-3-nitro­benzyl­idene)benzohydrazide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977221/
https://www.ncbi.nlm.nih.gov/pubmed/21583442
http://dx.doi.org/10.1107/S1600536809024131
work_keys_str_mv AT caoguobiao e3bromon4hydroxy3nitrobenzylidenebenzohydrazide
AT wangxiaoya e3bromon4hydroxy3nitrobenzylidenebenzohydrazide

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