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(E)-1-Methyl-2-styrylpyridinium iodide

In the title compound, C(14)H(14)N(+)·I(−), the cation exists in an E configuration with respect to the ethenyl bond and is slightly twisted, the inter­planar angle between the pyridinium and phenyl rings of the cation being 4.8 (2)°. In the crystal packing, the cations are stacked in an anti­parall...

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Detalles Bibliográficos
Autores principales: Fun, Hoong-Kun, Chanawanno, Kullapa, Chantrapromma, Suchada
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977224/
https://www.ncbi.nlm.nih.gov/pubmed/21583617
http://dx.doi.org/10.1107/S1600536809027810
Descripción
Sumario:In the title compound, C(14)H(14)N(+)·I(−), the cation exists in an E configuration with respect to the ethenyl bond and is slightly twisted, the inter­planar angle between the pyridinium and phenyl rings of the cation being 4.8 (2)°. In the crystal packing, the cations are stacked in an anti­parallel fashion along the a axis by a π–π inter­action involving both pyridinium and phenyl rings; the centroid–centroid distance is 3.542 (3) Å. Each iodide ion is sandwiched between two cations. The cations and iodide anions are linked together by weak C—H⋯I inter­actions, giving rise to ladder-like ribbons along the a axis.