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(E)-1-Methyl-2-styrylpyridinium iodide

In the title compound, C(14)H(14)N(+)·I(−), the cation exists in an E configuration with respect to the ethenyl bond and is slightly twisted, the inter­planar angle between the pyridinium and phenyl rings of the cation being 4.8 (2)°. In the crystal packing, the cations are stacked in an anti­parall...

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Autores principales: Fun, Hoong-Kun, Chanawanno, Kullapa, Chantrapromma, Suchada
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977224/
https://www.ncbi.nlm.nih.gov/pubmed/21583617
http://dx.doi.org/10.1107/S1600536809027810
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author Fun, Hoong-Kun
Chanawanno, Kullapa
Chantrapromma, Suchada
author_facet Fun, Hoong-Kun
Chanawanno, Kullapa
Chantrapromma, Suchada
author_sort Fun, Hoong-Kun
collection PubMed
description In the title compound, C(14)H(14)N(+)·I(−), the cation exists in an E configuration with respect to the ethenyl bond and is slightly twisted, the inter­planar angle between the pyridinium and phenyl rings of the cation being 4.8 (2)°. In the crystal packing, the cations are stacked in an anti­parallel fashion along the a axis by a π–π inter­action involving both pyridinium and phenyl rings; the centroid–centroid distance is 3.542 (3) Å. Each iodide ion is sandwiched between two cations. The cations and iodide anions are linked together by weak C—H⋯I inter­actions, giving rise to ladder-like ribbons along the a axis.
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spelling pubmed-29772242010-12-30 (E)-1-Methyl-2-styrylpyridinium iodide Fun, Hoong-Kun Chanawanno, Kullapa Chantrapromma, Suchada Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(14)H(14)N(+)·I(−), the cation exists in an E configuration with respect to the ethenyl bond and is slightly twisted, the inter­planar angle between the pyridinium and phenyl rings of the cation being 4.8 (2)°. In the crystal packing, the cations are stacked in an anti­parallel fashion along the a axis by a π–π inter­action involving both pyridinium and phenyl rings; the centroid–centroid distance is 3.542 (3) Å. Each iodide ion is sandwiched between two cations. The cations and iodide anions are linked together by weak C—H⋯I inter­actions, giving rise to ladder-like ribbons along the a axis. International Union of Crystallography 2009-07-18 /pmc/articles/PMC2977224/ /pubmed/21583617 http://dx.doi.org/10.1107/S1600536809027810 Text en © Fun et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Fun, Hoong-Kun
Chanawanno, Kullapa
Chantrapromma, Suchada
(E)-1-Methyl-2-styrylpyridinium iodide
title (E)-1-Methyl-2-styrylpyridinium iodide
title_full (E)-1-Methyl-2-styrylpyridinium iodide
title_fullStr (E)-1-Methyl-2-styrylpyridinium iodide
title_full_unstemmed (E)-1-Methyl-2-styrylpyridinium iodide
title_short (E)-1-Methyl-2-styrylpyridinium iodide
title_sort (e)-1-methyl-2-styrylpyridinium iodide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977224/
https://www.ncbi.nlm.nih.gov/pubmed/21583617
http://dx.doi.org/10.1107/S1600536809027810
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