Cargando…
(E)-1-Methyl-2-styrylpyridinium iodide
In the title compound, C(14)H(14)N(+)·I(−), the cation exists in an E configuration with respect to the ethenyl bond and is slightly twisted, the interplanar angle between the pyridinium and phenyl rings of the cation being 4.8 (2)°. In the crystal packing, the cations are stacked in an antiparall...
Autores principales: | , , |
---|---|
Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977224/ https://www.ncbi.nlm.nih.gov/pubmed/21583617 http://dx.doi.org/10.1107/S1600536809027810 |
_version_ | 1782191056942530560 |
---|---|
author | Fun, Hoong-Kun Chanawanno, Kullapa Chantrapromma, Suchada |
author_facet | Fun, Hoong-Kun Chanawanno, Kullapa Chantrapromma, Suchada |
author_sort | Fun, Hoong-Kun |
collection | PubMed |
description | In the title compound, C(14)H(14)N(+)·I(−), the cation exists in an E configuration with respect to the ethenyl bond and is slightly twisted, the interplanar angle between the pyridinium and phenyl rings of the cation being 4.8 (2)°. In the crystal packing, the cations are stacked in an antiparallel fashion along the a axis by a π–π interaction involving both pyridinium and phenyl rings; the centroid–centroid distance is 3.542 (3) Å. Each iodide ion is sandwiched between two cations. The cations and iodide anions are linked together by weak C—H⋯I interactions, giving rise to ladder-like ribbons along the a axis. |
format | Text |
id | pubmed-2977224 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29772242010-12-30 (E)-1-Methyl-2-styrylpyridinium iodide Fun, Hoong-Kun Chanawanno, Kullapa Chantrapromma, Suchada Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(14)H(14)N(+)·I(−), the cation exists in an E configuration with respect to the ethenyl bond and is slightly twisted, the interplanar angle between the pyridinium and phenyl rings of the cation being 4.8 (2)°. In the crystal packing, the cations are stacked in an antiparallel fashion along the a axis by a π–π interaction involving both pyridinium and phenyl rings; the centroid–centroid distance is 3.542 (3) Å. Each iodide ion is sandwiched between two cations. The cations and iodide anions are linked together by weak C—H⋯I interactions, giving rise to ladder-like ribbons along the a axis. International Union of Crystallography 2009-07-18 /pmc/articles/PMC2977224/ /pubmed/21583617 http://dx.doi.org/10.1107/S1600536809027810 Text en © Fun et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Fun, Hoong-Kun Chanawanno, Kullapa Chantrapromma, Suchada (E)-1-Methyl-2-styrylpyridinium iodide |
title | (E)-1-Methyl-2-styrylpyridinium iodide |
title_full | (E)-1-Methyl-2-styrylpyridinium iodide |
title_fullStr | (E)-1-Methyl-2-styrylpyridinium iodide |
title_full_unstemmed | (E)-1-Methyl-2-styrylpyridinium iodide |
title_short | (E)-1-Methyl-2-styrylpyridinium iodide |
title_sort | (e)-1-methyl-2-styrylpyridinium iodide |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977224/ https://www.ncbi.nlm.nih.gov/pubmed/21583617 http://dx.doi.org/10.1107/S1600536809027810 |
work_keys_str_mv | AT funhoongkun e1methyl2styrylpyridiniumiodide AT chanawannokullapa e1methyl2styrylpyridiniumiodide AT chantraprommasuchada e1methyl2styrylpyridiniumiodide |