catena-Poly[[(ethanol-κO)[3-(1-phenyl-1H-pyrazol-3-yl)benzoic acid-κO]lithium]-μ-3-(1-phenyl-1H-pyrazol-3-yl)benzoato-κ(2) O:O′]

The asymmetric unit of the title polymeric compound, [Li(2)(C(16)H(11)N(2)O(2))(2)(C(16)H(12)N(2)O(2))(2)(CH(3)CH(2)OH)(2)](n), contains two Li(I) ions, two 3-(1-phenyl-1H-pyrazol-3-yl)benzoate ions, two 3-(1-phenyl-1H-pyrazol-3-yl)benzoic acid mol­ecules and two ethanol mol­ecules. In the crystal s...

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Detalles Bibliográficos
Autores principales: Fun, Hoong-Kun, Balasubramani, Kasthuri, Rai, Sankappa, Shetty, Prakash, Isloor, Arun M.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977228/
https://www.ncbi.nlm.nih.gov/pubmed/21583374
http://dx.doi.org/10.1107/S1600536809026385
Descripción
Sumario:The asymmetric unit of the title polymeric compound, [Li(2)(C(16)H(11)N(2)O(2))(2)(C(16)H(12)N(2)O(2))(2)(CH(3)CH(2)OH)(2)](n), contains two Li(I) ions, two 3-(1-phenyl-1H-pyrazol-3-yl)benzoate ions, two 3-(1-phenyl-1H-pyrazol-3-yl)benzoic acid mol­ecules and two ethanol mol­ecules. In the crystal structure, each of the two Li(I) ions has a distorted tetra­hedral geometry, coordinated by two carboxyl­ate O atoms, one carboxyl O atom and one ethanol O atom. The carboxyl­ate group bridges the Li(I) ions, forming a one-dimensional polymeric chain along [100]. The crystal structure is further stabilized by O—H⋯O and C—H⋯N hydrogen bonding, and π–π inter­actions with centroid–centroid distances in the range 3.6534 (13)–3.8374 (13) Å.

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