catena-Poly[[(ethanol-κO)[3-(1-phenyl-1H-pyrazol-3-yl)benzoic acid-κO]lithium]-μ-3-(1-phenyl-1H-pyrazol-3-yl)benzoato-κ(2) O:O′]

The asymmetric unit of the title polymeric compound, [Li(2)(C(16)H(11)N(2)O(2))(2)(C(16)H(12)N(2)O(2))(2)(CH(3)CH(2)OH)(2)](n), contains two Li(I) ions, two 3-(1-phenyl-1H-pyrazol-3-yl)benzoate ions, two 3-(1-phenyl-1H-pyrazol-3-yl)benzoic acid mol­ecules and two ethanol mol­ecules. In the crystal s...

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Detalles Bibliográficos
Autores principales: Fun, Hoong-Kun, Balasubramani, Kasthuri, Rai, Sankappa, Shetty, Prakash, Isloor, Arun M.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977228/
https://www.ncbi.nlm.nih.gov/pubmed/21583374
http://dx.doi.org/10.1107/S1600536809026385
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author Fun, Hoong-Kun
Balasubramani, Kasthuri
Rai, Sankappa
Shetty, Prakash
Isloor, Arun M.
author_facet Fun, Hoong-Kun
Balasubramani, Kasthuri
Rai, Sankappa
Shetty, Prakash
Isloor, Arun M.
author_sort Fun, Hoong-Kun
collection PubMed
description The asymmetric unit of the title polymeric compound, [Li(2)(C(16)H(11)N(2)O(2))(2)(C(16)H(12)N(2)O(2))(2)(CH(3)CH(2)OH)(2)](n), contains two Li(I) ions, two 3-(1-phenyl-1H-pyrazol-3-yl)benzoate ions, two 3-(1-phenyl-1H-pyrazol-3-yl)benzoic acid mol­ecules and two ethanol mol­ecules. In the crystal structure, each of the two Li(I) ions has a distorted tetra­hedral geometry, coordinated by two carboxyl­ate O atoms, one carboxyl O atom and one ethanol O atom. The carboxyl­ate group bridges the Li(I) ions, forming a one-dimensional polymeric chain along [100]. The crystal structure is further stabilized by O—H⋯O and C—H⋯N hydrogen bonding, and π–π inter­actions with centroid–centroid distances in the range 3.6534 (13)–3.8374 (13) Å.
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spelling pubmed-29772282010-12-30 catena-Poly[[(ethanol-κO)[3-(1-phenyl-1H-pyrazol-3-yl)benzoic acid-κO]lithium]-μ-3-(1-phenyl-1H-pyrazol-3-yl)benzoato-κ(2) O:O′] Fun, Hoong-Kun Balasubramani, Kasthuri Rai, Sankappa Shetty, Prakash Isloor, Arun M. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title polymeric compound, [Li(2)(C(16)H(11)N(2)O(2))(2)(C(16)H(12)N(2)O(2))(2)(CH(3)CH(2)OH)(2)](n), contains two Li(I) ions, two 3-(1-phenyl-1H-pyrazol-3-yl)benzoate ions, two 3-(1-phenyl-1H-pyrazol-3-yl)benzoic acid mol­ecules and two ethanol mol­ecules. In the crystal structure, each of the two Li(I) ions has a distorted tetra­hedral geometry, coordinated by two carboxyl­ate O atoms, one carboxyl O atom and one ethanol O atom. The carboxyl­ate group bridges the Li(I) ions, forming a one-dimensional polymeric chain along [100]. The crystal structure is further stabilized by O—H⋯O and C—H⋯N hydrogen bonding, and π–π inter­actions with centroid–centroid distances in the range 3.6534 (13)–3.8374 (13) Å. International Union of Crystallography 2009-07-15 /pmc/articles/PMC2977228/ /pubmed/21583374 http://dx.doi.org/10.1107/S1600536809026385 Text en © Fun et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Fun, Hoong-Kun
Balasubramani, Kasthuri
Rai, Sankappa
Shetty, Prakash
Isloor, Arun M.
catena-Poly[[(ethanol-κO)[3-(1-phenyl-1H-pyrazol-3-yl)benzoic acid-κO]lithium]-μ-3-(1-phenyl-1H-pyrazol-3-yl)benzoato-κ(2) O:O′]
title catena-Poly[[(ethanol-κO)[3-(1-phenyl-1H-pyrazol-3-yl)benzoic acid-κO]lithium]-μ-3-(1-phenyl-1H-pyrazol-3-yl)benzoato-κ(2) O:O′]
title_full catena-Poly[[(ethanol-κO)[3-(1-phenyl-1H-pyrazol-3-yl)benzoic acid-κO]lithium]-μ-3-(1-phenyl-1H-pyrazol-3-yl)benzoato-κ(2) O:O′]
title_fullStr catena-Poly[[(ethanol-κO)[3-(1-phenyl-1H-pyrazol-3-yl)benzoic acid-κO]lithium]-μ-3-(1-phenyl-1H-pyrazol-3-yl)benzoato-κ(2) O:O′]
title_full_unstemmed catena-Poly[[(ethanol-κO)[3-(1-phenyl-1H-pyrazol-3-yl)benzoic acid-κO]lithium]-μ-3-(1-phenyl-1H-pyrazol-3-yl)benzoato-κ(2) O:O′]
title_short catena-Poly[[(ethanol-κO)[3-(1-phenyl-1H-pyrazol-3-yl)benzoic acid-κO]lithium]-μ-3-(1-phenyl-1H-pyrazol-3-yl)benzoato-κ(2) O:O′]
title_sort catena-poly[[(ethanol-κo)[3-(1-phenyl-1h-pyrazol-3-yl)benzoic acid-κo]lithium]-μ-3-(1-phenyl-1h-pyrazol-3-yl)benzoato-κ(2) o:o′]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977228/
https://www.ncbi.nlm.nih.gov/pubmed/21583374
http://dx.doi.org/10.1107/S1600536809026385
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