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Bis{2-[(2-pyrid­yl)imino­meth­yl]phenolato}copper(II)

In the title compound, [Cu(C(12)H(9)N(2)O)(2)], the Cu(II) atom lies on a crystallographic inversion center and has a nearly square-planar geometry. The Cu(II) center coordinates to the phenolic O and azomethine N atoms of the two symmetry-related 2-[(2-pyrid­yl)imino­meth­yl]phenolate ligands. The...

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Detalles Bibliográficos
Autores principales: Miao, Jinling, Zhao, Zhitong, Chen, Hongwei, Wang, Daqi, Nie, Yong
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977229/
https://www.ncbi.nlm.nih.gov/pubmed/21583364
http://dx.doi.org/10.1107/S1600536809026051
Descripción
Sumario:In the title compound, [Cu(C(12)H(9)N(2)O)(2)], the Cu(II) atom lies on a crystallographic inversion center and has a nearly square-planar geometry. The Cu(II) center coordinates to the phenolic O and azomethine N atoms of the two symmetry-related 2-[(2-pyrid­yl)imino­meth­yl]phenolate ligands. The pyridyl N atoms do not coordinate to the Cu(II) atom but participate in intra­molecular C—H⋯N hydrogen bonding. π–π stacking between the benzene rings and between the pyridyl rings [centroid–centroid distances 3.8142 (5) and 3.8142 (5) Å, respectively] links the mol­ecules into a chain propagating parallel to [100].