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Bis{2-[(2-pyridyl)iminomethyl]phenolato}copper(II)
In the title compound, [Cu(C(12)H(9)N(2)O)(2)], the Cu(II) atom lies on a crystallographic inversion center and has a nearly square-planar geometry. The Cu(II) center coordinates to the phenolic O and azomethine N atoms of the two symmetry-related 2-[(2-pyridyl)iminomethyl]phenolate ligands. The...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977229/ https://www.ncbi.nlm.nih.gov/pubmed/21583364 http://dx.doi.org/10.1107/S1600536809026051 |
Sumario: | In the title compound, [Cu(C(12)H(9)N(2)O)(2)], the Cu(II) atom lies on a crystallographic inversion center and has a nearly square-planar geometry. The Cu(II) center coordinates to the phenolic O and azomethine N atoms of the two symmetry-related 2-[(2-pyridyl)iminomethyl]phenolate ligands. The pyridyl N atoms do not coordinate to the Cu(II) atom but participate in intramolecular C—H⋯N hydrogen bonding. π–π stacking between the benzene rings and between the pyridyl rings [centroid–centroid distances 3.8142 (5) and 3.8142 (5) Å, respectively] links the molecules into a chain propagating parallel to [100]. |
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