[1,1′-Bis(diphenyl­phosphino)cobalto­cenium-κ(2) P,P′]dichloridoplatinum(II) hexa­fluorido­phosphate

The title bimetallic compound, [PtCl(2){Co(C(17)H(14)P)(2)}]PF(6), was obtained by reaction of 1,1′-bis­(diphenyl­phosphino)cobalto­cenium hexa­fluorido­phosphate with bis­(acetonitrile)di­chloridoplatinum. The Pt(II) ion is four-coordinated in a slightly distorted square-planar environment by two P...

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Detalles Bibliográficos
Autores principales: Guan, Jin-Tao, Zhang, Kai-Cheng, Dai, Zhi-Qun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977235/
https://www.ncbi.nlm.nih.gov/pubmed/21583406
http://dx.doi.org/10.1107/S1600536809027925
Descripción
Sumario:The title bimetallic compound, [PtCl(2){Co(C(17)H(14)P)(2)}]PF(6), was obtained by reaction of 1,1′-bis­(diphenyl­phosphino)cobalto­cenium hexa­fluorido­phosphate with bis­(acetonitrile)di­chloridoplatinum. The Pt(II) ion is four-coordinated in a slightly distorted square-planar environment by two P atoms of the 1,1′-bis­(diphenyl­phosphino)cobaltocenium moiety and two Cl atoms. In the crystal structure, mol­ecules are linked by weak C—H⋯F and C—H⋯Cl hydrogen bonds.

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