Cargando…
2-(2,4-Dichlorophenyl)-9-phenyl-2,3-dihydrothieno[3,2-b]quinoline
In the title compound, C(23)H(15)Cl(2)NS, the quinoline system is almost planar [r.m.s. deviation = 0.013 (2) Å]. The phenyl group is disordered over two positions with site occupancies of 0.55 and 0.45, and is oriented in a nearly perpendicular configuration to the quinoline ring [the dihedral angl...
Autores principales: | , , , , |
---|---|
Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977236/ https://www.ncbi.nlm.nih.gov/pubmed/21583489 http://dx.doi.org/10.1107/S1600536809025380 |
_version_ | 1782191059748519936 |
---|---|
author | Balamurugan, K. Narmadha, D. Suresh, J. Perumal, S. Lakshman, P. L. Nilantha |
author_facet | Balamurugan, K. Narmadha, D. Suresh, J. Perumal, S. Lakshman, P. L. Nilantha |
author_sort | Balamurugan, K. |
collection | PubMed |
description | In the title compound, C(23)H(15)Cl(2)NS, the quinoline system is almost planar [r.m.s. deviation = 0.013 (2) Å]. The phenyl group is disordered over two positions with site occupancies of 0.55 and 0.45, and is oriented in a nearly perpendicular configuration to the quinoline ring [the dihedral angles between the quinoline ring and the major and minor disordered components of the phenyl ring are 81.8 (2) and 71.6 (2)°, respectively]. The dihydrothiene ring adopts an envelope conformation. The dihedral angle between the chlorophenyl ring and the quinoline system is 79.32 (1)°. In the crystal weak C—H⋯π interactions occur. |
format | Text |
id | pubmed-2977236 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29772362010-12-30 2-(2,4-Dichlorophenyl)-9-phenyl-2,3-dihydrothieno[3,2-b]quinoline Balamurugan, K. Narmadha, D. Suresh, J. Perumal, S. Lakshman, P. L. Nilantha Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(23)H(15)Cl(2)NS, the quinoline system is almost planar [r.m.s. deviation = 0.013 (2) Å]. The phenyl group is disordered over two positions with site occupancies of 0.55 and 0.45, and is oriented in a nearly perpendicular configuration to the quinoline ring [the dihedral angles between the quinoline ring and the major and minor disordered components of the phenyl ring are 81.8 (2) and 71.6 (2)°, respectively]. The dihydrothiene ring adopts an envelope conformation. The dihedral angle between the chlorophenyl ring and the quinoline system is 79.32 (1)°. In the crystal weak C—H⋯π interactions occur. International Union of Crystallography 2009-07-04 /pmc/articles/PMC2977236/ /pubmed/21583489 http://dx.doi.org/10.1107/S1600536809025380 Text en © Balamurugan et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Balamurugan, K. Narmadha, D. Suresh, J. Perumal, S. Lakshman, P. L. Nilantha 2-(2,4-Dichlorophenyl)-9-phenyl-2,3-dihydrothieno[3,2-b]quinoline |
title | 2-(2,4-Dichlorophenyl)-9-phenyl-2,3-dihydrothieno[3,2-b]quinoline |
title_full | 2-(2,4-Dichlorophenyl)-9-phenyl-2,3-dihydrothieno[3,2-b]quinoline |
title_fullStr | 2-(2,4-Dichlorophenyl)-9-phenyl-2,3-dihydrothieno[3,2-b]quinoline |
title_full_unstemmed | 2-(2,4-Dichlorophenyl)-9-phenyl-2,3-dihydrothieno[3,2-b]quinoline |
title_short | 2-(2,4-Dichlorophenyl)-9-phenyl-2,3-dihydrothieno[3,2-b]quinoline |
title_sort | 2-(2,4-dichlorophenyl)-9-phenyl-2,3-dihydrothieno[3,2-b]quinoline |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977236/ https://www.ncbi.nlm.nih.gov/pubmed/21583489 http://dx.doi.org/10.1107/S1600536809025380 |
work_keys_str_mv | AT balamurugank 224dichlorophenyl9phenyl23dihydrothieno32bquinoline AT narmadhad 224dichlorophenyl9phenyl23dihydrothieno32bquinoline AT sureshj 224dichlorophenyl9phenyl23dihydrothieno32bquinoline AT perumals 224dichlorophenyl9phenyl23dihydrothieno32bquinoline AT lakshmanplnilantha 224dichlorophenyl9phenyl23dihydrothieno32bquinoline |