Cargando…

2-(2,4-Dichloro­phen­yl)-9-phenyl-2,3-di­hydro­thieno[3,2-b]quinoline

In the title compound, C(23)H(15)Cl(2)NS, the quinoline system is almost planar [r.m.s. deviation = 0.013 (2) Å]. The phenyl group is disordered over two positions with site occupancies of 0.55 and 0.45, and is oriented in a nearly perpendicular configuration to the quinoline ring [the dihedral angl...

Descripción completa

Detalles Bibliográficos
Autores principales: Balamurugan, K., Narmadha, D., Suresh, J., Perumal, S., Lakshman, P. L. Nilantha
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977236/
https://www.ncbi.nlm.nih.gov/pubmed/21583489
http://dx.doi.org/10.1107/S1600536809025380
_version_ 1782191059748519936
author Balamurugan, K.
Narmadha, D.
Suresh, J.
Perumal, S.
Lakshman, P. L. Nilantha
author_facet Balamurugan, K.
Narmadha, D.
Suresh, J.
Perumal, S.
Lakshman, P. L. Nilantha
author_sort Balamurugan, K.
collection PubMed
description In the title compound, C(23)H(15)Cl(2)NS, the quinoline system is almost planar [r.m.s. deviation = 0.013 (2) Å]. The phenyl group is disordered over two positions with site occupancies of 0.55 and 0.45, and is oriented in a nearly perpendicular configuration to the quinoline ring [the dihedral angles between the quinoline ring and the major and minor disordered components of the phenyl ring are 81.8 (2) and 71.6 (2)°, respectively]. The dihydro­thiene ring adopts an envelope conformation. The dihedral angle between the chloro­phenyl ring and the quinoline system is 79.32 (1)°. In the crystal weak C—H⋯π inter­actions occur.
format Text
id pubmed-2977236
institution National Center for Biotechnology Information
language English
publishDate 2009
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29772362010-12-30 2-(2,4-Dichloro­phen­yl)-9-phenyl-2,3-di­hydro­thieno[3,2-b]quinoline Balamurugan, K. Narmadha, D. Suresh, J. Perumal, S. Lakshman, P. L. Nilantha Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(23)H(15)Cl(2)NS, the quinoline system is almost planar [r.m.s. deviation = 0.013 (2) Å]. The phenyl group is disordered over two positions with site occupancies of 0.55 and 0.45, and is oriented in a nearly perpendicular configuration to the quinoline ring [the dihedral angles between the quinoline ring and the major and minor disordered components of the phenyl ring are 81.8 (2) and 71.6 (2)°, respectively]. The dihydro­thiene ring adopts an envelope conformation. The dihedral angle between the chloro­phenyl ring and the quinoline system is 79.32 (1)°. In the crystal weak C—H⋯π inter­actions occur. International Union of Crystallography 2009-07-04 /pmc/articles/PMC2977236/ /pubmed/21583489 http://dx.doi.org/10.1107/S1600536809025380 Text en © Balamurugan et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Balamurugan, K.
Narmadha, D.
Suresh, J.
Perumal, S.
Lakshman, P. L. Nilantha
2-(2,4-Dichloro­phen­yl)-9-phenyl-2,3-di­hydro­thieno[3,2-b]quinoline
title 2-(2,4-Dichloro­phen­yl)-9-phenyl-2,3-di­hydro­thieno[3,2-b]quinoline
title_full 2-(2,4-Dichloro­phen­yl)-9-phenyl-2,3-di­hydro­thieno[3,2-b]quinoline
title_fullStr 2-(2,4-Dichloro­phen­yl)-9-phenyl-2,3-di­hydro­thieno[3,2-b]quinoline
title_full_unstemmed 2-(2,4-Dichloro­phen­yl)-9-phenyl-2,3-di­hydro­thieno[3,2-b]quinoline
title_short 2-(2,4-Dichloro­phen­yl)-9-phenyl-2,3-di­hydro­thieno[3,2-b]quinoline
title_sort 2-(2,4-dichloro­phen­yl)-9-phenyl-2,3-di­hydro­thieno[3,2-b]quinoline
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977236/
https://www.ncbi.nlm.nih.gov/pubmed/21583489
http://dx.doi.org/10.1107/S1600536809025380
work_keys_str_mv AT balamurugank 224dichlorophenyl9phenyl23dihydrothieno32bquinoline
AT narmadhad 224dichlorophenyl9phenyl23dihydrothieno32bquinoline
AT sureshj 224dichlorophenyl9phenyl23dihydrothieno32bquinoline
AT perumals 224dichlorophenyl9phenyl23dihydrothieno32bquinoline
AT lakshmanplnilantha 224dichlorophenyl9phenyl23dihydrothieno32bquinoline