Aqua­(furan-2-carboxyl­ato-κO)(furan-2-carboxyl­ato-κ(2) O,O′)(1,10-phenanthroline-κ(2) N,N′)copper(II) methanol hemisolvate

The asymmetric unit of the title compound, [Cu(C(5)H(3)O(3))(2)(C(12)H(8)N(2))(2)(H(2)O)]·0.5CH(3)OH, contains two Cu(II) complex mol­ecules and one methanol solvent mol­ecule with the metal centres in strongly distorted octahedral coordination. The coordinated water mol­ecule is involved in inter­m...

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Detalles Bibliográficos
Autores principales: Li, Yanfei, Sun, Junshan, Feng, Shanghua, Xue, Ruigang, Wang, Jun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977238/
https://www.ncbi.nlm.nih.gov/pubmed/21583326
http://dx.doi.org/10.1107/S1600536809024428
Descripción
Sumario:The asymmetric unit of the title compound, [Cu(C(5)H(3)O(3))(2)(C(12)H(8)N(2))(2)(H(2)O)]·0.5CH(3)OH, contains two Cu(II) complex mol­ecules and one methanol solvent mol­ecule with the metal centres in strongly distorted octahedral coordination. The coordinated water mol­ecule is involved in inter­molecular O—H⋯O hydrogen bonding, which links the complex mol­ecules into chains propagating along the c axis. Neighbouring chains inter­act further via π–π inter­actions between the aromatic rings of 1,10-phenanthroline fragments [centroid–centroid distances = 3.726 (4) and 3.750 (4) Å].

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