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Di-μ-chlorido-bis[aqua(2,2′-bipyridine-κ(2) N,N′)chloridocobalt(II)]
The title complex, [Co(2)Cl(4)(C(10)H(8)N(2))(2)(H(2)O)(2)], is composed of two Co(II) atoms, each hexacoordinated by three Cl atoms, one 2,2′-bipyridine (bpy) ligand and one water molecule in a distorted octahedral geometry. Neighboring Co(II) atoms are linked together by two Cl bridges, forming...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977247/ https://www.ncbi.nlm.nih.gov/pubmed/21583432 http://dx.doi.org/10.1107/S1600536809027846 |
Sumario: | The title complex, [Co(2)Cl(4)(C(10)H(8)N(2))(2)(H(2)O)(2)], is composed of two Co(II) atoms, each hexacoordinated by three Cl atoms, one 2,2′-bipyridine (bpy) ligand and one water molecule in a distorted octahedral geometry. Neighboring Co(II) atoms are linked together by two Cl bridges, forming a dinuclear Co(II) complex with inversion symmetry. There are intermolecular O—H⋯Cl hydrogen bonds and intermolecular π–π stacking interactions between adjacent bpy ligands [centroid–centroid distance = 3.617 (2) Å] in the structure. |
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