Di-μ-chlorido-bis­[aqua­(2,2′-bipyridine-κ(2) N,N′)chloridocobalt(II)]

The title complex, [Co(2)Cl(4)(C(10)H(8)N(2))(2)(H(2)O)(2)], is composed of two Co(II) atoms, each hexa­coordinated by three Cl atoms, one 2,2′-bipyridine (bpy) ligand and one water mol­ecule in a distorted octa­hedral geometry. Neighboring Co(II) atoms are linked together by two Cl bridges, forming...

Descripción completa

Detalles Bibliográficos
Autores principales: Zhu, Li-Li, Sun, Yu, Zhang, Huai-Hong, Wang, Yun, Sun, Bai-Wang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977247/
https://www.ncbi.nlm.nih.gov/pubmed/21583432
http://dx.doi.org/10.1107/S1600536809027846
_version_ 1782191062438117376
author Zhu, Li-Li
Sun, Yu
Zhang, Huai-Hong
Wang, Yun
Sun, Bai-Wang
author_facet Zhu, Li-Li
Sun, Yu
Zhang, Huai-Hong
Wang, Yun
Sun, Bai-Wang
author_sort Zhu, Li-Li
collection PubMed
description The title complex, [Co(2)Cl(4)(C(10)H(8)N(2))(2)(H(2)O)(2)], is composed of two Co(II) atoms, each hexa­coordinated by three Cl atoms, one 2,2′-bipyridine (bpy) ligand and one water mol­ecule in a distorted octa­hedral geometry. Neighboring Co(II) atoms are linked together by two Cl bridges, forming a dinuclear Co(II) complex with inversion symmetry. There are inter­molecular O—H⋯Cl hydrogen bonds and inter­molecular π–π stacking inter­actions between adjacent bpy ligands [centroid–centroid distance = 3.617 (2) Å] in the structure.
format Text
id pubmed-2977247
institution National Center for Biotechnology Information
language English
publishDate 2009
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29772472010-12-30 Di-μ-chlorido-bis­[aqua­(2,2′-bipyridine-κ(2) N,N′)chloridocobalt(II)] Zhu, Li-Li Sun, Yu Zhang, Huai-Hong Wang, Yun Sun, Bai-Wang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title complex, [Co(2)Cl(4)(C(10)H(8)N(2))(2)(H(2)O)(2)], is composed of two Co(II) atoms, each hexa­coordinated by three Cl atoms, one 2,2′-bipyridine (bpy) ligand and one water mol­ecule in a distorted octa­hedral geometry. Neighboring Co(II) atoms are linked together by two Cl bridges, forming a dinuclear Co(II) complex with inversion symmetry. There are inter­molecular O—H⋯Cl hydrogen bonds and inter­molecular π–π stacking inter­actions between adjacent bpy ligands [centroid–centroid distance = 3.617 (2) Å] in the structure. International Union of Crystallography 2009-07-25 /pmc/articles/PMC2977247/ /pubmed/21583432 http://dx.doi.org/10.1107/S1600536809027846 Text en © Zhu et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhu, Li-Li
Sun, Yu
Zhang, Huai-Hong
Wang, Yun
Sun, Bai-Wang
Di-μ-chlorido-bis­[aqua­(2,2′-bipyridine-κ(2) N,N′)chloridocobalt(II)]
title Di-μ-chlorido-bis­[aqua­(2,2′-bipyridine-κ(2) N,N′)chloridocobalt(II)]
title_full Di-μ-chlorido-bis­[aqua­(2,2′-bipyridine-κ(2) N,N′)chloridocobalt(II)]
title_fullStr Di-μ-chlorido-bis­[aqua­(2,2′-bipyridine-κ(2) N,N′)chloridocobalt(II)]
title_full_unstemmed Di-μ-chlorido-bis­[aqua­(2,2′-bipyridine-κ(2) N,N′)chloridocobalt(II)]
title_short Di-μ-chlorido-bis­[aqua­(2,2′-bipyridine-κ(2) N,N′)chloridocobalt(II)]
title_sort di-μ-chlorido-bis­[aqua­(2,2′-bipyridine-κ(2) n,n′)chloridocobalt(ii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977247/
https://www.ncbi.nlm.nih.gov/pubmed/21583432
http://dx.doi.org/10.1107/S1600536809027846
work_keys_str_mv AT zhulili dimchloridobisaqua22bipyridinek2nnchloridocobaltii
AT sunyu dimchloridobisaqua22bipyridinek2nnchloridocobaltii
AT zhanghuaihong dimchloridobisaqua22bipyridinek2nnchloridocobaltii
AT wangyun dimchloridobisaqua22bipyridinek2nnchloridocobaltii
AT sunbaiwang dimchloridobisaqua22bipyridinek2nnchloridocobaltii

Ejemplares similares