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N-[2-(6-Methyl-4-oxo-4H-chromen-3-yl)-4-oxothiazolidin-3-yl]furan-2-carboxamide N,N-dimethylformamide solvate
The title molecule, C(18)H(14)N(2)O(5)S·C(3)H(7)NO, comprises of a carboxamide group bonded to a furan ring and a distorted envelope-shaped 4-oxothiazolidin-3-yl group which is connected to a substituted 6-methyl-4-oxo-4H-chromen-3-yl group. Extensive strong N—H⋯O and weak C—H⋯O intermolecular hy...
Autores principales: | , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977248/ https://www.ncbi.nlm.nih.gov/pubmed/21583697 http://dx.doi.org/10.1107/S1600536809029572 |
Sumario: | The title molecule, C(18)H(14)N(2)O(5)S·C(3)H(7)NO, comprises of a carboxamide group bonded to a furan ring and a distorted envelope-shaped 4-oxothiazolidin-3-yl group which is connected to a substituted 6-methyl-4-oxo-4H-chromen-3-yl group. Extensive strong N—H⋯O and weak C—H⋯O intermolecular hydrogen-bonding interactions occur between dimethylformamide (DMF), the crystallizing solvent, and the various heterocyclic groups within the compound, as well as additional weak C—H⋯O interactions between the heterocyclic groups themselves. The carboxyl group of the DMF solvent molecule forms a trifurcated (four-center) acceptor hydrogen-bond interaction with the carboxamide, furan and 6-methyl-4-oxo-4H-chromen-3-yl groups. The dihedral angles between the planar chromone group [maximum deviation = 0.0377 (18)°] and those of the furan and 4-oxothiazolidin-3-yl groups are 89.4 (6) and 78.5 (1)°, respectively. |
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