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N-[2-(6-Methyl-4-oxo-4H-chromen-3-yl)-4-oxothia­zolidin-3-yl]furan-2-carbox­amide N,N-dimethyl­formamide solvate

The title mol­ecule, C(18)H(14)N(2)O(5)S·C(3)H(7)NO, comprises of a carboxamide group bonded to a furan ring and a distorted envelope-shaped 4-oxothia­zolidin-3-yl group which is connected to a substituted 6-methyl-4-oxo-4H-chromen-3-yl group. Extensive strong N—H⋯O and weak C—H⋯O inter­molecular hy...

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Autores principales: Zhao, Pei-Liang, Zhou, Zhong-Zhen
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977248/
https://www.ncbi.nlm.nih.gov/pubmed/21583697
http://dx.doi.org/10.1107/S1600536809029572
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author Zhao, Pei-Liang
Zhou, Zhong-Zhen
author_facet Zhao, Pei-Liang
Zhou, Zhong-Zhen
author_sort Zhao, Pei-Liang
collection PubMed
description The title mol­ecule, C(18)H(14)N(2)O(5)S·C(3)H(7)NO, comprises of a carboxamide group bonded to a furan ring and a distorted envelope-shaped 4-oxothia­zolidin-3-yl group which is connected to a substituted 6-methyl-4-oxo-4H-chromen-3-yl group. Extensive strong N—H⋯O and weak C—H⋯O inter­molecular hydrogen-bonding inter­actions occur between dimethyl­formamide (DMF), the crystallizing solvent, and the various heterocyclic groups within the compound, as well as additional weak C—H⋯O inter­actions between the heterocyclic groups themselves. The carboxyl group of the DMF solvent mol­ecule forms a trifurcated (four-center) acceptor hydrogen-bond inter­action with the carboxamide, furan and 6-methyl-4-oxo-4H-chromen-3-yl groups. The dihedral angles between the planar chromone group [maximum deviation = 0.0377 (18)°] and those of the furan and 4-oxothia­zolidin-3-yl groups are 89.4 (6) and 78.5 (1)°, respectively.
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spelling pubmed-29772482010-12-30 N-[2-(6-Methyl-4-oxo-4H-chromen-3-yl)-4-oxothia­zolidin-3-yl]furan-2-carbox­amide N,N-dimethyl­formamide solvate Zhao, Pei-Liang Zhou, Zhong-Zhen Acta Crystallogr Sect E Struct Rep Online Organic Papers The title mol­ecule, C(18)H(14)N(2)O(5)S·C(3)H(7)NO, comprises of a carboxamide group bonded to a furan ring and a distorted envelope-shaped 4-oxothia­zolidin-3-yl group which is connected to a substituted 6-methyl-4-oxo-4H-chromen-3-yl group. Extensive strong N—H⋯O and weak C—H⋯O inter­molecular hydrogen-bonding inter­actions occur between dimethyl­formamide (DMF), the crystallizing solvent, and the various heterocyclic groups within the compound, as well as additional weak C—H⋯O inter­actions between the heterocyclic groups themselves. The carboxyl group of the DMF solvent mol­ecule forms a trifurcated (four-center) acceptor hydrogen-bond inter­action with the carboxamide, furan and 6-methyl-4-oxo-4H-chromen-3-yl groups. The dihedral angles between the planar chromone group [maximum deviation = 0.0377 (18)°] and those of the furan and 4-oxothia­zolidin-3-yl groups are 89.4 (6) and 78.5 (1)°, respectively. International Union of Crystallography 2009-07-29 /pmc/articles/PMC2977248/ /pubmed/21583697 http://dx.doi.org/10.1107/S1600536809029572 Text en © Zhao and Zhou 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Zhao, Pei-Liang
Zhou, Zhong-Zhen
N-[2-(6-Methyl-4-oxo-4H-chromen-3-yl)-4-oxothia­zolidin-3-yl]furan-2-carbox­amide N,N-dimethyl­formamide solvate
title N-[2-(6-Methyl-4-oxo-4H-chromen-3-yl)-4-oxothia­zolidin-3-yl]furan-2-carbox­amide N,N-dimethyl­formamide solvate
title_full N-[2-(6-Methyl-4-oxo-4H-chromen-3-yl)-4-oxothia­zolidin-3-yl]furan-2-carbox­amide N,N-dimethyl­formamide solvate
title_fullStr N-[2-(6-Methyl-4-oxo-4H-chromen-3-yl)-4-oxothia­zolidin-3-yl]furan-2-carbox­amide N,N-dimethyl­formamide solvate
title_full_unstemmed N-[2-(6-Methyl-4-oxo-4H-chromen-3-yl)-4-oxothia­zolidin-3-yl]furan-2-carbox­amide N,N-dimethyl­formamide solvate
title_short N-[2-(6-Methyl-4-oxo-4H-chromen-3-yl)-4-oxothia­zolidin-3-yl]furan-2-carbox­amide N,N-dimethyl­formamide solvate
title_sort n-[2-(6-methyl-4-oxo-4h-chromen-3-yl)-4-oxothia­zolidin-3-yl]furan-2-carbox­amide n,n-dimethyl­formamide solvate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977248/
https://www.ncbi.nlm.nih.gov/pubmed/21583697
http://dx.doi.org/10.1107/S1600536809029572
work_keys_str_mv AT zhaopeiliang n26methyl4oxo4hchromen3yl4oxothiazolidin3ylfuran2carboxamidenndimethylformamidesolvate
AT zhouzhongzhen n26methyl4oxo4hchromen3yl4oxothiazolidin3ylfuran2carboxamidenndimethylformamidesolvate