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N-[2-(6-Methyl-4-oxo-4H-chromen-3-yl)-4-oxothiazolidin-3-yl]furan-2-carboxamide N,N-dimethylformamide solvate
The title molecule, C(18)H(14)N(2)O(5)S·C(3)H(7)NO, comprises of a carboxamide group bonded to a furan ring and a distorted envelope-shaped 4-oxothiazolidin-3-yl group which is connected to a substituted 6-methyl-4-oxo-4H-chromen-3-yl group. Extensive strong N—H⋯O and weak C—H⋯O intermolecular hy...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2009
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977248/ https://www.ncbi.nlm.nih.gov/pubmed/21583697 http://dx.doi.org/10.1107/S1600536809029572 |
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author | Zhao, Pei-Liang Zhou, Zhong-Zhen |
author_facet | Zhao, Pei-Liang Zhou, Zhong-Zhen |
author_sort | Zhao, Pei-Liang |
collection | PubMed |
description | The title molecule, C(18)H(14)N(2)O(5)S·C(3)H(7)NO, comprises of a carboxamide group bonded to a furan ring and a distorted envelope-shaped 4-oxothiazolidin-3-yl group which is connected to a substituted 6-methyl-4-oxo-4H-chromen-3-yl group. Extensive strong N—H⋯O and weak C—H⋯O intermolecular hydrogen-bonding interactions occur between dimethylformamide (DMF), the crystallizing solvent, and the various heterocyclic groups within the compound, as well as additional weak C—H⋯O interactions between the heterocyclic groups themselves. The carboxyl group of the DMF solvent molecule forms a trifurcated (four-center) acceptor hydrogen-bond interaction with the carboxamide, furan and 6-methyl-4-oxo-4H-chromen-3-yl groups. The dihedral angles between the planar chromone group [maximum deviation = 0.0377 (18)°] and those of the furan and 4-oxothiazolidin-3-yl groups are 89.4 (6) and 78.5 (1)°, respectively. |
format | Text |
id | pubmed-2977248 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29772482010-12-30 N-[2-(6-Methyl-4-oxo-4H-chromen-3-yl)-4-oxothiazolidin-3-yl]furan-2-carboxamide N,N-dimethylformamide solvate Zhao, Pei-Liang Zhou, Zhong-Zhen Acta Crystallogr Sect E Struct Rep Online Organic Papers The title molecule, C(18)H(14)N(2)O(5)S·C(3)H(7)NO, comprises of a carboxamide group bonded to a furan ring and a distorted envelope-shaped 4-oxothiazolidin-3-yl group which is connected to a substituted 6-methyl-4-oxo-4H-chromen-3-yl group. Extensive strong N—H⋯O and weak C—H⋯O intermolecular hydrogen-bonding interactions occur between dimethylformamide (DMF), the crystallizing solvent, and the various heterocyclic groups within the compound, as well as additional weak C—H⋯O interactions between the heterocyclic groups themselves. The carboxyl group of the DMF solvent molecule forms a trifurcated (four-center) acceptor hydrogen-bond interaction with the carboxamide, furan and 6-methyl-4-oxo-4H-chromen-3-yl groups. The dihedral angles between the planar chromone group [maximum deviation = 0.0377 (18)°] and those of the furan and 4-oxothiazolidin-3-yl groups are 89.4 (6) and 78.5 (1)°, respectively. International Union of Crystallography 2009-07-29 /pmc/articles/PMC2977248/ /pubmed/21583697 http://dx.doi.org/10.1107/S1600536809029572 Text en © Zhao and Zhou 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Zhao, Pei-Liang Zhou, Zhong-Zhen N-[2-(6-Methyl-4-oxo-4H-chromen-3-yl)-4-oxothiazolidin-3-yl]furan-2-carboxamide N,N-dimethylformamide solvate |
title |
N-[2-(6-Methyl-4-oxo-4H-chromen-3-yl)-4-oxothiazolidin-3-yl]furan-2-carboxamide N,N-dimethylformamide solvate |
title_full |
N-[2-(6-Methyl-4-oxo-4H-chromen-3-yl)-4-oxothiazolidin-3-yl]furan-2-carboxamide N,N-dimethylformamide solvate |
title_fullStr |
N-[2-(6-Methyl-4-oxo-4H-chromen-3-yl)-4-oxothiazolidin-3-yl]furan-2-carboxamide N,N-dimethylformamide solvate |
title_full_unstemmed |
N-[2-(6-Methyl-4-oxo-4H-chromen-3-yl)-4-oxothiazolidin-3-yl]furan-2-carboxamide N,N-dimethylformamide solvate |
title_short |
N-[2-(6-Methyl-4-oxo-4H-chromen-3-yl)-4-oxothiazolidin-3-yl]furan-2-carboxamide N,N-dimethylformamide solvate |
title_sort | n-[2-(6-methyl-4-oxo-4h-chromen-3-yl)-4-oxothiazolidin-3-yl]furan-2-carboxamide n,n-dimethylformamide solvate |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977248/ https://www.ncbi.nlm.nih.gov/pubmed/21583697 http://dx.doi.org/10.1107/S1600536809029572 |
work_keys_str_mv | AT zhaopeiliang n26methyl4oxo4hchromen3yl4oxothiazolidin3ylfuran2carboxamidenndimethylformamidesolvate AT zhouzhongzhen n26methyl4oxo4hchromen3yl4oxothiazolidin3ylfuran2carboxamidenndimethylformamidesolvate |