Cargando…

Hemiaqua­bis(2-fluoro­benzoato-κ(2) O,O′)bis­(1,10-phenanthroline-κ(2) N,N′)lead(II) dihydrate

In the title compound, [Pb(C(7)H(4)FO(2))(2)(C(12)H(8)N(2))(2)(H(2)O)(0.5)]·2H(2)O, the Pb(II) atom is coordinated by four N atoms from two bidentate chelating 1,10-phenanthroline (phen) ligands, four O atoms from two 2-fluoro­benzoate ligands and a half-occupied water mol­ecule in an irregular coor...

Descripción completa

Detalles Bibliográficos
Autores principales: Ye, Su-Fang, Zhang, Bi-Song
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977250/
https://www.ncbi.nlm.nih.gov/pubmed/21583389
http://dx.doi.org/10.1107/S1600536809027524
Descripción
Sumario:In the title compound, [Pb(C(7)H(4)FO(2))(2)(C(12)H(8)N(2))(2)(H(2)O)(0.5)]·2H(2)O, the Pb(II) atom is coordinated by four N atoms from two bidentate chelating 1,10-phenanthroline (phen) ligands, four O atoms from two 2-fluoro­benzoate ligands and a half-occupied water mol­ecule in an irregular coordination geometry. One carboxyl­ate O atom and two F atoms are each disordered over two sites with occupancy factors of 0.558 (6) and 0.442 (6). The two crystallographically independent phen ligands are co-planar [dihedral angle 0.0 (2)°]. Centroid–centroid distances of 3.659 (7) and 3.687 (7) Å indicate π–π stacking inter­actions between neighboring phen ligands. In the crystal, O—H⋯O, C—H⋯F and C—H⋯O hydrogen bonds link the complex mol­ecules and uncoordinated water mol­ecules into a supra­molecular network.