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Hemiaqua­bis(2-fluoro­benzoato-κ(2) O,O′)bis­(1,10-phenanthroline-κ(2) N,N′)lead(II) dihydrate

In the title compound, [Pb(C(7)H(4)FO(2))(2)(C(12)H(8)N(2))(2)(H(2)O)(0.5)]·2H(2)O, the Pb(II) atom is coordinated by four N atoms from two bidentate chelating 1,10-phenanthroline (phen) ligands, four O atoms from two 2-fluoro­benzoate ligands and a half-occupied water mol­ecule in an irregular coor...

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Autores principales: Ye, Su-Fang, Zhang, Bi-Song
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977250/
https://www.ncbi.nlm.nih.gov/pubmed/21583389
http://dx.doi.org/10.1107/S1600536809027524
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author Ye, Su-Fang
Zhang, Bi-Song
author_facet Ye, Su-Fang
Zhang, Bi-Song
author_sort Ye, Su-Fang
collection PubMed
description In the title compound, [Pb(C(7)H(4)FO(2))(2)(C(12)H(8)N(2))(2)(H(2)O)(0.5)]·2H(2)O, the Pb(II) atom is coordinated by four N atoms from two bidentate chelating 1,10-phenanthroline (phen) ligands, four O atoms from two 2-fluoro­benzoate ligands and a half-occupied water mol­ecule in an irregular coordination geometry. One carboxyl­ate O atom and two F atoms are each disordered over two sites with occupancy factors of 0.558 (6) and 0.442 (6). The two crystallographically independent phen ligands are co-planar [dihedral angle 0.0 (2)°]. Centroid–centroid distances of 3.659 (7) and 3.687 (7) Å indicate π–π stacking inter­actions between neighboring phen ligands. In the crystal, O—H⋯O, C—H⋯F and C—H⋯O hydrogen bonds link the complex mol­ecules and uncoordinated water mol­ecules into a supra­molecular network.
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spelling pubmed-29772502010-12-30 Hemiaqua­bis(2-fluoro­benzoato-κ(2) O,O′)bis­(1,10-phenanthroline-κ(2) N,N′)lead(II) dihydrate Ye, Su-Fang Zhang, Bi-Song Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Pb(C(7)H(4)FO(2))(2)(C(12)H(8)N(2))(2)(H(2)O)(0.5)]·2H(2)O, the Pb(II) atom is coordinated by four N atoms from two bidentate chelating 1,10-phenanthroline (phen) ligands, four O atoms from two 2-fluoro­benzoate ligands and a half-occupied water mol­ecule in an irregular coordination geometry. One carboxyl­ate O atom and two F atoms are each disordered over two sites with occupancy factors of 0.558 (6) and 0.442 (6). The two crystallographically independent phen ligands are co-planar [dihedral angle 0.0 (2)°]. Centroid–centroid distances of 3.659 (7) and 3.687 (7) Å indicate π–π stacking inter­actions between neighboring phen ligands. In the crystal, O—H⋯O, C—H⋯F and C—H⋯O hydrogen bonds link the complex mol­ecules and uncoordinated water mol­ecules into a supra­molecular network. International Union of Crystallography 2009-07-18 /pmc/articles/PMC2977250/ /pubmed/21583389 http://dx.doi.org/10.1107/S1600536809027524 Text en © Ye and Zhang 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Ye, Su-Fang
Zhang, Bi-Song
Hemiaqua­bis(2-fluoro­benzoato-κ(2) O,O′)bis­(1,10-phenanthroline-κ(2) N,N′)lead(II) dihydrate
title Hemiaqua­bis(2-fluoro­benzoato-κ(2) O,O′)bis­(1,10-phenanthroline-κ(2) N,N′)lead(II) dihydrate
title_full Hemiaqua­bis(2-fluoro­benzoato-κ(2) O,O′)bis­(1,10-phenanthroline-κ(2) N,N′)lead(II) dihydrate
title_fullStr Hemiaqua­bis(2-fluoro­benzoato-κ(2) O,O′)bis­(1,10-phenanthroline-κ(2) N,N′)lead(II) dihydrate
title_full_unstemmed Hemiaqua­bis(2-fluoro­benzoato-κ(2) O,O′)bis­(1,10-phenanthroline-κ(2) N,N′)lead(II) dihydrate
title_short Hemiaqua­bis(2-fluoro­benzoato-κ(2) O,O′)bis­(1,10-phenanthroline-κ(2) N,N′)lead(II) dihydrate
title_sort hemiaqua­bis(2-fluoro­benzoato-κ(2) o,o′)bis­(1,10-phenanthroline-κ(2) n,n′)lead(ii) dihydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977250/
https://www.ncbi.nlm.nih.gov/pubmed/21583389
http://dx.doi.org/10.1107/S1600536809027524
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