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Hemiaquabis(2-fluorobenzoato-κ(2) O,O′)bis(1,10-phenanthroline-κ(2) N,N′)lead(II) dihydrate
In the title compound, [Pb(C(7)H(4)FO(2))(2)(C(12)H(8)N(2))(2)(H(2)O)(0.5)]·2H(2)O, the Pb(II) atom is coordinated by four N atoms from two bidentate chelating 1,10-phenanthroline (phen) ligands, four O atoms from two 2-fluorobenzoate ligands and a half-occupied water molecule in an irregular coor...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977250/ https://www.ncbi.nlm.nih.gov/pubmed/21583389 http://dx.doi.org/10.1107/S1600536809027524 |
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author | Ye, Su-Fang Zhang, Bi-Song |
author_facet | Ye, Su-Fang Zhang, Bi-Song |
author_sort | Ye, Su-Fang |
collection | PubMed |
description | In the title compound, [Pb(C(7)H(4)FO(2))(2)(C(12)H(8)N(2))(2)(H(2)O)(0.5)]·2H(2)O, the Pb(II) atom is coordinated by four N atoms from two bidentate chelating 1,10-phenanthroline (phen) ligands, four O atoms from two 2-fluorobenzoate ligands and a half-occupied water molecule in an irregular coordination geometry. One carboxylate O atom and two F atoms are each disordered over two sites with occupancy factors of 0.558 (6) and 0.442 (6). The two crystallographically independent phen ligands are co-planar [dihedral angle 0.0 (2)°]. Centroid–centroid distances of 3.659 (7) and 3.687 (7) Å indicate π–π stacking interactions between neighboring phen ligands. In the crystal, O—H⋯O, C—H⋯F and C—H⋯O hydrogen bonds link the complex molecules and uncoordinated water molecules into a supramolecular network. |
format | Text |
id | pubmed-2977250 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29772502010-12-30 Hemiaquabis(2-fluorobenzoato-κ(2) O,O′)bis(1,10-phenanthroline-κ(2) N,N′)lead(II) dihydrate Ye, Su-Fang Zhang, Bi-Song Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Pb(C(7)H(4)FO(2))(2)(C(12)H(8)N(2))(2)(H(2)O)(0.5)]·2H(2)O, the Pb(II) atom is coordinated by four N atoms from two bidentate chelating 1,10-phenanthroline (phen) ligands, four O atoms from two 2-fluorobenzoate ligands and a half-occupied water molecule in an irregular coordination geometry. One carboxylate O atom and two F atoms are each disordered over two sites with occupancy factors of 0.558 (6) and 0.442 (6). The two crystallographically independent phen ligands are co-planar [dihedral angle 0.0 (2)°]. Centroid–centroid distances of 3.659 (7) and 3.687 (7) Å indicate π–π stacking interactions between neighboring phen ligands. In the crystal, O—H⋯O, C—H⋯F and C—H⋯O hydrogen bonds link the complex molecules and uncoordinated water molecules into a supramolecular network. International Union of Crystallography 2009-07-18 /pmc/articles/PMC2977250/ /pubmed/21583389 http://dx.doi.org/10.1107/S1600536809027524 Text en © Ye and Zhang 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Ye, Su-Fang Zhang, Bi-Song Hemiaquabis(2-fluorobenzoato-κ(2) O,O′)bis(1,10-phenanthroline-κ(2) N,N′)lead(II) dihydrate |
title | Hemiaquabis(2-fluorobenzoato-κ(2)
O,O′)bis(1,10-phenanthroline-κ(2)
N,N′)lead(II) dihydrate |
title_full | Hemiaquabis(2-fluorobenzoato-κ(2)
O,O′)bis(1,10-phenanthroline-κ(2)
N,N′)lead(II) dihydrate |
title_fullStr | Hemiaquabis(2-fluorobenzoato-κ(2)
O,O′)bis(1,10-phenanthroline-κ(2)
N,N′)lead(II) dihydrate |
title_full_unstemmed | Hemiaquabis(2-fluorobenzoato-κ(2)
O,O′)bis(1,10-phenanthroline-κ(2)
N,N′)lead(II) dihydrate |
title_short | Hemiaquabis(2-fluorobenzoato-κ(2)
O,O′)bis(1,10-phenanthroline-κ(2)
N,N′)lead(II) dihydrate |
title_sort | hemiaquabis(2-fluorobenzoato-κ(2)
o,o′)bis(1,10-phenanthroline-κ(2)
n,n′)lead(ii) dihydrate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977250/ https://www.ncbi.nlm.nih.gov/pubmed/21583389 http://dx.doi.org/10.1107/S1600536809027524 |
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