[μ-1,1′-(Butane-1,4-di­yl)di-1H-benz­imidazole-κ(2) N (3):N (3′)]bis­{[N,N′-bis(car­boxy­meth­yl)ethyl­enediamine-N,N′-di­acetato-κ(5) O,O′,O′′,N,N′]mercury(II)} methanol disolvate

The binuclear title complex, [Hg(2)(C(10)H(14)N(2)O(8))(2)(C(18)H(18)N(4))]·2CH(3)OH, lies on an inversion center with the unique Hg(II) ion coordinated in a disorted octa­hedral environment with one Hg—N bond significantly shorter than the other two. In the crystal structure, inter­molecular O—H⋯O...

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Detalles Bibliográficos
Autores principales: Zhu, Xue-Wen, Xiao, Bo, Yin, Zhi-Gang, Qian, Heng-Yu, Li, Gang-Sen
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977252/
https://www.ncbi.nlm.nih.gov/pubmed/21583370
http://dx.doi.org/10.1107/S1600536809026221
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author Zhu, Xue-Wen
Xiao, Bo
Yin, Zhi-Gang
Qian, Heng-Yu
Li, Gang-Sen
author_facet Zhu, Xue-Wen
Xiao, Bo
Yin, Zhi-Gang
Qian, Heng-Yu
Li, Gang-Sen
author_sort Zhu, Xue-Wen
collection PubMed
description The binuclear title complex, [Hg(2)(C(10)H(14)N(2)O(8))(2)(C(18)H(18)N(4))]·2CH(3)OH, lies on an inversion center with the unique Hg(II) ion coordinated in a disorted octa­hedral environment with one Hg—N bond significantly shorter than the other two. In the crystal structure, inter­molecular O—H⋯O hydrogen bonds link complex and solvent mol­ecules into a three-dimensional network.
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spelling pubmed-29772522010-12-30 [μ-1,1′-(Butane-1,4-di­yl)di-1H-benz­imidazole-κ(2) N (3):N (3′)]bis­{[N,N′-bis(car­boxy­meth­yl)ethyl­enediamine-N,N′-di­acetato-κ(5) O,O′,O′′,N,N′]mercury(II)} methanol disolvate Zhu, Xue-Wen Xiao, Bo Yin, Zhi-Gang Qian, Heng-Yu Li, Gang-Sen Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The binuclear title complex, [Hg(2)(C(10)H(14)N(2)O(8))(2)(C(18)H(18)N(4))]·2CH(3)OH, lies on an inversion center with the unique Hg(II) ion coordinated in a disorted octa­hedral environment with one Hg—N bond significantly shorter than the other two. In the crystal structure, inter­molecular O—H⋯O hydrogen bonds link complex and solvent mol­ecules into a three-dimensional network. International Union of Crystallography 2009-07-11 /pmc/articles/PMC2977252/ /pubmed/21583370 http://dx.doi.org/10.1107/S1600536809026221 Text en © Zhu et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhu, Xue-Wen
Xiao, Bo
Yin, Zhi-Gang
Qian, Heng-Yu
Li, Gang-Sen
[μ-1,1′-(Butane-1,4-di­yl)di-1H-benz­imidazole-κ(2) N (3):N (3′)]bis­{[N,N′-bis(car­boxy­meth­yl)ethyl­enediamine-N,N′-di­acetato-κ(5) O,O′,O′′,N,N′]mercury(II)} methanol disolvate
title [μ-1,1′-(Butane-1,4-di­yl)di-1H-benz­imidazole-κ(2) N (3):N (3′)]bis­{[N,N′-bis(car­boxy­meth­yl)ethyl­enediamine-N,N′-di­acetato-κ(5) O,O′,O′′,N,N′]mercury(II)} methanol disolvate
title_full [μ-1,1′-(Butane-1,4-di­yl)di-1H-benz­imidazole-κ(2) N (3):N (3′)]bis­{[N,N′-bis(car­boxy­meth­yl)ethyl­enediamine-N,N′-di­acetato-κ(5) O,O′,O′′,N,N′]mercury(II)} methanol disolvate
title_fullStr [μ-1,1′-(Butane-1,4-di­yl)di-1H-benz­imidazole-κ(2) N (3):N (3′)]bis­{[N,N′-bis(car­boxy­meth­yl)ethyl­enediamine-N,N′-di­acetato-κ(5) O,O′,O′′,N,N′]mercury(II)} methanol disolvate
title_full_unstemmed [μ-1,1′-(Butane-1,4-di­yl)di-1H-benz­imidazole-κ(2) N (3):N (3′)]bis­{[N,N′-bis(car­boxy­meth­yl)ethyl­enediamine-N,N′-di­acetato-κ(5) O,O′,O′′,N,N′]mercury(II)} methanol disolvate
title_short [μ-1,1′-(Butane-1,4-di­yl)di-1H-benz­imidazole-κ(2) N (3):N (3′)]bis­{[N,N′-bis(car­boxy­meth­yl)ethyl­enediamine-N,N′-di­acetato-κ(5) O,O′,O′′,N,N′]mercury(II)} methanol disolvate
title_sort [μ-1,1′-(butane-1,4-di­yl)di-1h-benz­imidazole-κ(2) n (3):n (3′)]bis­{[n,n′-bis(car­boxy­meth­yl)ethyl­enediamine-n,n′-di­acetato-κ(5) o,o′,o′′,n,n′]mercury(ii)} methanol disolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977252/
https://www.ncbi.nlm.nih.gov/pubmed/21583370
http://dx.doi.org/10.1107/S1600536809026221
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