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N (2),N (2),N (4),N (4)-Tetraethyl-6-{2-[(E)-1-(4-nitrophenyl)ethylidene]hydrazino}-1,3,5-triazine-2,4-diamine
The title compound, C(19)H(28)N(8)O(2), was prepared by the reaction of N (2),N (2),N (4),N (4)-tetraethyl-6-hydrazino-1,3,5-triazine-2,4-diamine and 1-(4-nitrophenyl)ethanone in ethanol at room temperature. The molecular conformation is stabilized by intramolecular C—H⋯N hydrogen-bonding inter...
Autores principales: | , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977253/ https://www.ncbi.nlm.nih.gov/pubmed/21583544 http://dx.doi.org/10.1107/S1600536809025677 |
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author | Pan, Xiao-Ru Jian, Fang-Fang |
author_facet | Pan, Xiao-Ru Jian, Fang-Fang |
author_sort | Pan, Xiao-Ru |
collection | PubMed |
description | The title compound, C(19)H(28)N(8)O(2), was prepared by the reaction of N (2),N (2),N (4),N (4)-tetraethyl-6-hydrazino-1,3,5-triazine-2,4-diamine and 1-(4-nitrophenyl)ethanone in ethanol at room temperature. The molecular conformation is stabilized by intramolecular C—H⋯N hydrogen-bonding interactions. There are also intermolecular N—H⋯O hydrogen bonds, and C—H⋯π and π–π interactions, which help to stabilize the crystal structure. The centroid–centroid distance is 3.6172 (10) Å between adjacent benzene and 1,3,5-triazine rings. |
format | Text |
id | pubmed-2977253 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29772532010-12-30 N (2),N (2),N (4),N (4)-Tetraethyl-6-{2-[(E)-1-(4-nitrophenyl)ethylidene]hydrazino}-1,3,5-triazine-2,4-diamine Pan, Xiao-Ru Jian, Fang-Fang Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(19)H(28)N(8)O(2), was prepared by the reaction of N (2),N (2),N (4),N (4)-tetraethyl-6-hydrazino-1,3,5-triazine-2,4-diamine and 1-(4-nitrophenyl)ethanone in ethanol at room temperature. The molecular conformation is stabilized by intramolecular C—H⋯N hydrogen-bonding interactions. There are also intermolecular N—H⋯O hydrogen bonds, and C—H⋯π and π–π interactions, which help to stabilize the crystal structure. The centroid–centroid distance is 3.6172 (10) Å between adjacent benzene and 1,3,5-triazine rings. International Union of Crystallography 2009-07-11 /pmc/articles/PMC2977253/ /pubmed/21583544 http://dx.doi.org/10.1107/S1600536809025677 Text en © Pan and Jian 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Pan, Xiao-Ru Jian, Fang-Fang N (2),N (2),N (4),N (4)-Tetraethyl-6-{2-[(E)-1-(4-nitrophenyl)ethylidene]hydrazino}-1,3,5-triazine-2,4-diamine |
title |
N
(2),N
(2),N
(4),N
(4)-Tetraethyl-6-{2-[(E)-1-(4-nitrophenyl)ethylidene]hydrazino}-1,3,5-triazine-2,4-diamine |
title_full |
N
(2),N
(2),N
(4),N
(4)-Tetraethyl-6-{2-[(E)-1-(4-nitrophenyl)ethylidene]hydrazino}-1,3,5-triazine-2,4-diamine |
title_fullStr |
N
(2),N
(2),N
(4),N
(4)-Tetraethyl-6-{2-[(E)-1-(4-nitrophenyl)ethylidene]hydrazino}-1,3,5-triazine-2,4-diamine |
title_full_unstemmed |
N
(2),N
(2),N
(4),N
(4)-Tetraethyl-6-{2-[(E)-1-(4-nitrophenyl)ethylidene]hydrazino}-1,3,5-triazine-2,4-diamine |
title_short |
N
(2),N
(2),N
(4),N
(4)-Tetraethyl-6-{2-[(E)-1-(4-nitrophenyl)ethylidene]hydrazino}-1,3,5-triazine-2,4-diamine |
title_sort | n
(2),n
(2),n
(4),n
(4)-tetraethyl-6-{2-[(e)-1-(4-nitrophenyl)ethylidene]hydrazino}-1,3,5-triazine-2,4-diamine |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977253/ https://www.ncbi.nlm.nih.gov/pubmed/21583544 http://dx.doi.org/10.1107/S1600536809025677 |
work_keys_str_mv | AT panxiaoru n2n2n4n4tetraethyl62e14nitrophenylethylidenehydrazino135triazine24diamine AT jianfangfang n2n2n4n4tetraethyl62e14nitrophenylethylidenehydrazino135triazine24diamine |