Cargando…

N (2),N (2),N (4),N (4)-Tetra­ethyl-6-{2-[(E)-1-(4-nitro­phen­yl)ethyl­idene]hydrazino}-1,3,5-triazine-2,4-diamine

The title compound, C(19)H(28)N(8)O(2), was prepared by the reaction of N (2),N (2),N (4),N (4)-tetra­ethyl-6-hydrazino-1,3,5-triazine-2,4-diamine and 1-(4-nitro­phen­yl)ethanone in ethanol at room temperature. The mol­ecular conformation is stabilized by intra­molecular C—H⋯N hydrogen-bonding inter...

Descripción completa

Detalles Bibliográficos
Autores principales: Pan, Xiao-Ru, Jian, Fang-Fang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977253/
https://www.ncbi.nlm.nih.gov/pubmed/21583544
http://dx.doi.org/10.1107/S1600536809025677
_version_ 1782191063844257792
author Pan, Xiao-Ru
Jian, Fang-Fang
author_facet Pan, Xiao-Ru
Jian, Fang-Fang
author_sort Pan, Xiao-Ru
collection PubMed
description The title compound, C(19)H(28)N(8)O(2), was prepared by the reaction of N (2),N (2),N (4),N (4)-tetra­ethyl-6-hydrazino-1,3,5-triazine-2,4-diamine and 1-(4-nitro­phen­yl)ethanone in ethanol at room temperature. The mol­ecular conformation is stabilized by intra­molecular C—H⋯N hydrogen-bonding inter­actions. There are also inter­molecular N—H⋯O hydrogen bonds, and C—H⋯π and π–π inter­actions, which help to stabilize the crystal structure. The centroid–centroid distance is 3.6172 (10) Å between adjacent benzene and 1,3,5-triazine rings.
format Text
id pubmed-2977253
institution National Center for Biotechnology Information
language English
publishDate 2009
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29772532010-12-30 N (2),N (2),N (4),N (4)-Tetra­ethyl-6-{2-[(E)-1-(4-nitro­phen­yl)ethyl­idene]hydrazino}-1,3,5-triazine-2,4-diamine Pan, Xiao-Ru Jian, Fang-Fang Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(19)H(28)N(8)O(2), was prepared by the reaction of N (2),N (2),N (4),N (4)-tetra­ethyl-6-hydrazino-1,3,5-triazine-2,4-diamine and 1-(4-nitro­phen­yl)ethanone in ethanol at room temperature. The mol­ecular conformation is stabilized by intra­molecular C—H⋯N hydrogen-bonding inter­actions. There are also inter­molecular N—H⋯O hydrogen bonds, and C—H⋯π and π–π inter­actions, which help to stabilize the crystal structure. The centroid–centroid distance is 3.6172 (10) Å between adjacent benzene and 1,3,5-triazine rings. International Union of Crystallography 2009-07-11 /pmc/articles/PMC2977253/ /pubmed/21583544 http://dx.doi.org/10.1107/S1600536809025677 Text en © Pan and Jian 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Pan, Xiao-Ru
Jian, Fang-Fang
N (2),N (2),N (4),N (4)-Tetra­ethyl-6-{2-[(E)-1-(4-nitro­phen­yl)ethyl­idene]hydrazino}-1,3,5-triazine-2,4-diamine
title N (2),N (2),N (4),N (4)-Tetra­ethyl-6-{2-[(E)-1-(4-nitro­phen­yl)ethyl­idene]hydrazino}-1,3,5-triazine-2,4-diamine
title_full N (2),N (2),N (4),N (4)-Tetra­ethyl-6-{2-[(E)-1-(4-nitro­phen­yl)ethyl­idene]hydrazino}-1,3,5-triazine-2,4-diamine
title_fullStr N (2),N (2),N (4),N (4)-Tetra­ethyl-6-{2-[(E)-1-(4-nitro­phen­yl)ethyl­idene]hydrazino}-1,3,5-triazine-2,4-diamine
title_full_unstemmed N (2),N (2),N (4),N (4)-Tetra­ethyl-6-{2-[(E)-1-(4-nitro­phen­yl)ethyl­idene]hydrazino}-1,3,5-triazine-2,4-diamine
title_short N (2),N (2),N (4),N (4)-Tetra­ethyl-6-{2-[(E)-1-(4-nitro­phen­yl)ethyl­idene]hydrazino}-1,3,5-triazine-2,4-diamine
title_sort n (2),n (2),n (4),n (4)-tetra­ethyl-6-{2-[(e)-1-(4-nitro­phen­yl)ethyl­idene]hydrazino}-1,3,5-triazine-2,4-diamine
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977253/
https://www.ncbi.nlm.nih.gov/pubmed/21583544
http://dx.doi.org/10.1107/S1600536809025677
work_keys_str_mv AT panxiaoru n2n2n4n4tetraethyl62e14nitrophenylethylidenehydrazino135triazine24diamine
AT jianfangfang n2n2n4n4tetraethyl62e14nitrophenylethylidenehydrazino135triazine24diamine