2-(3-Pyridinio)benzimidazolium penta­chloridobismuthate(III) monohydrate

In the title compound, (C(12)H(11)N(3))[BiCl(5)]·H(2)O, the Bi(III) atom is coordinated by five chloride anions in a distorted square-pyramidal geometry. The planar imidazole ring system [maximum deviation = 0.012 (3) Å] is oriented at a dihedral angle of 6.08 (5)° with respect to the protonated pyr...

Descripción completa

Detalles Bibliográficos
Autores principales: Cui, Li-Jing, Xu, Hai-Jun, Pang, Yi-Jie
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977254/
https://www.ncbi.nlm.nih.gov/pubmed/21583321
http://dx.doi.org/10.1107/S1600536809024568
_version_ 1782191064070750208
author Cui, Li-Jing
Xu, Hai-Jun
Pang, Yi-Jie
author_facet Cui, Li-Jing
Xu, Hai-Jun
Pang, Yi-Jie
author_sort Cui, Li-Jing
collection PubMed
description In the title compound, (C(12)H(11)N(3))[BiCl(5)]·H(2)O, the Bi(III) atom is coordinated by five chloride anions in a distorted square-pyramidal geometry. The planar imidazole ring system [maximum deviation = 0.012 (3) Å] is oriented at a dihedral angle of 6.08 (5)° with respect to the protonated pyridine ring. An O—H⋯Cl inter­action links the water mol­ecule to the dianion. In the crystal structure, inter­molecular O—H⋯Cl, N—H⋯O and N—H⋯Cl inter­actions link the mol­ecules into a three-dimensional network.
format Text
id pubmed-2977254
institution National Center for Biotechnology Information
language English
publishDate 2009
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29772542010-12-30 2-(3-Pyridinio)benzimidazolium penta­chloridobismuthate(III) monohydrate Cui, Li-Jing Xu, Hai-Jun Pang, Yi-Jie Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, (C(12)H(11)N(3))[BiCl(5)]·H(2)O, the Bi(III) atom is coordinated by five chloride anions in a distorted square-pyramidal geometry. The planar imidazole ring system [maximum deviation = 0.012 (3) Å] is oriented at a dihedral angle of 6.08 (5)° with respect to the protonated pyridine ring. An O—H⋯Cl inter­action links the water mol­ecule to the dianion. In the crystal structure, inter­molecular O—H⋯Cl, N—H⋯O and N—H⋯Cl inter­actions link the mol­ecules into a three-dimensional network. International Union of Crystallography 2009-07-01 /pmc/articles/PMC2977254/ /pubmed/21583321 http://dx.doi.org/10.1107/S1600536809024568 Text en © Cui et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Cui, Li-Jing
Xu, Hai-Jun
Pang, Yi-Jie
2-(3-Pyridinio)benzimidazolium penta­chloridobismuthate(III) monohydrate
title 2-(3-Pyridinio)benzimidazolium penta­chloridobismuthate(III) monohydrate
title_full 2-(3-Pyridinio)benzimidazolium penta­chloridobismuthate(III) monohydrate
title_fullStr 2-(3-Pyridinio)benzimidazolium penta­chloridobismuthate(III) monohydrate
title_full_unstemmed 2-(3-Pyridinio)benzimidazolium penta­chloridobismuthate(III) monohydrate
title_short 2-(3-Pyridinio)benzimidazolium penta­chloridobismuthate(III) monohydrate
title_sort 2-(3-pyridinio)benzimidazolium penta­chloridobismuthate(iii) monohydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977254/
https://www.ncbi.nlm.nih.gov/pubmed/21583321
http://dx.doi.org/10.1107/S1600536809024568
work_keys_str_mv AT cuilijing 23pyridiniobenzimidazoliumpentachloridobismuthateiiimonohydrate
AT xuhaijun 23pyridiniobenzimidazoliumpentachloridobismuthateiiimonohydrate
AT pangyijie 23pyridiniobenzimidazoliumpentachloridobismuthateiiimonohydrate

Ejemplares similares