Di-μ-chlorido-bis­({2-[(4-bromo­phen­yl)­imino­meth­yl]pyridine-κ(2) N,N′}­chloridomercury(II))

The unique Hg(II) ion in the title centrosymmetric dinuclear complex, [Hg(2)Cl(4)(C(12)H(9)BrN(2))(2)], is in a distorted trigonal–bipyramidal coordination environment formed by the bis-chelating N-heterocyclic ligand, two bridging Cl atoms and one terminal Cl atom. One of the bridging Hg—Cl bonds i...

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Detalles Bibliográficos
Autores principales: Mahmoudi, Ali, Dehghanpour, Saeed, Khalaj, Mehdi, Pakravan, Shabnam
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977257/
https://www.ncbi.nlm.nih.gov/pubmed/21583352
http://dx.doi.org/10.1107/S1600536809025641
Descripción
Sumario:The unique Hg(II) ion in the title centrosymmetric dinuclear complex, [Hg(2)Cl(4)(C(12)H(9)BrN(2))(2)], is in a distorted trigonal–bipyramidal coordination environment formed by the bis-chelating N-heterocyclic ligand, two bridging Cl atoms and one terminal Cl atom. One of the bridging Hg—Cl bonds is significantly longer than the other.

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