Di-μ-chlorido-bis­({2-[(4-bromo­phen­yl)­imino­meth­yl]pyridine-κ(2) N,N′}­chloridomercury(II))

The unique Hg(II) ion in the title centrosymmetric dinuclear complex, [Hg(2)Cl(4)(C(12)H(9)BrN(2))(2)], is in a distorted trigonal–bipyramidal coordination environment formed by the bis-chelating N-heterocyclic ligand, two bridging Cl atoms and one terminal Cl atom. One of the bridging Hg—Cl bonds i...

Descripción completa

Detalles Bibliográficos
Autores principales: Mahmoudi, Ali, Dehghanpour, Saeed, Khalaj, Mehdi, Pakravan, Shabnam
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977257/
https://www.ncbi.nlm.nih.gov/pubmed/21583352
http://dx.doi.org/10.1107/S1600536809025641
_version_ 1782191064758616064
author Mahmoudi, Ali
Dehghanpour, Saeed
Khalaj, Mehdi
Pakravan, Shabnam
author_facet Mahmoudi, Ali
Dehghanpour, Saeed
Khalaj, Mehdi
Pakravan, Shabnam
author_sort Mahmoudi, Ali
collection PubMed
description The unique Hg(II) ion in the title centrosymmetric dinuclear complex, [Hg(2)Cl(4)(C(12)H(9)BrN(2))(2)], is in a distorted trigonal–bipyramidal coordination environment formed by the bis-chelating N-heterocyclic ligand, two bridging Cl atoms and one terminal Cl atom. One of the bridging Hg—Cl bonds is significantly longer than the other.
format Text
id pubmed-2977257
institution National Center for Biotechnology Information
language English
publishDate 2009
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29772572010-12-30 Di-μ-chlorido-bis­({2-[(4-bromo­phen­yl)­imino­meth­yl]pyridine-κ(2) N,N′}­chloridomercury(II)) Mahmoudi, Ali Dehghanpour, Saeed Khalaj, Mehdi Pakravan, Shabnam Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The unique Hg(II) ion in the title centrosymmetric dinuclear complex, [Hg(2)Cl(4)(C(12)H(9)BrN(2))(2)], is in a distorted trigonal–bipyramidal coordination environment formed by the bis-chelating N-heterocyclic ligand, two bridging Cl atoms and one terminal Cl atom. One of the bridging Hg—Cl bonds is significantly longer than the other. International Union of Crystallography 2009-07-11 /pmc/articles/PMC2977257/ /pubmed/21583352 http://dx.doi.org/10.1107/S1600536809025641 Text en © Mahmoudi et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Mahmoudi, Ali
Dehghanpour, Saeed
Khalaj, Mehdi
Pakravan, Shabnam
Di-μ-chlorido-bis­({2-[(4-bromo­phen­yl)­imino­meth­yl]pyridine-κ(2) N,N′}­chloridomercury(II))
title Di-μ-chlorido-bis­({2-[(4-bromo­phen­yl)­imino­meth­yl]pyridine-κ(2) N,N′}­chloridomercury(II))
title_full Di-μ-chlorido-bis­({2-[(4-bromo­phen­yl)­imino­meth­yl]pyridine-κ(2) N,N′}­chloridomercury(II))
title_fullStr Di-μ-chlorido-bis­({2-[(4-bromo­phen­yl)­imino­meth­yl]pyridine-κ(2) N,N′}­chloridomercury(II))
title_full_unstemmed Di-μ-chlorido-bis­({2-[(4-bromo­phen­yl)­imino­meth­yl]pyridine-κ(2) N,N′}­chloridomercury(II))
title_short Di-μ-chlorido-bis­({2-[(4-bromo­phen­yl)­imino­meth­yl]pyridine-κ(2) N,N′}­chloridomercury(II))
title_sort di-μ-chlorido-bis­({2-[(4-bromo­phen­yl)­imino­meth­yl]pyridine-κ(2) n,n′}­chloridomercury(ii))
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977257/
https://www.ncbi.nlm.nih.gov/pubmed/21583352
http://dx.doi.org/10.1107/S1600536809025641
work_keys_str_mv AT mahmoudiali dimchloridobis24bromophenyliminomethylpyridinek2nnchloridomercuryii
AT dehghanpoursaeed dimchloridobis24bromophenyliminomethylpyridinek2nnchloridomercuryii
AT khalajmehdi dimchloridobis24bromophenyliminomethylpyridinek2nnchloridomercuryii
AT pakravanshabnam dimchloridobis24bromophenyliminomethylpyridinek2nnchloridomercuryii

Ejemplares similares