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2-[2-Benzoyl-3,3-bis(methylsulfanyl)prop-2-enylidene]malononitrile
The title compound, C(15)H(12)N(2)OS(2), is an example of a push–pull butadiene in which the electron-releasing methylsulfanyl groups and electron-withdrawing nitrile groups on either end of the butadiene chain enhance the conjugation in the system. Short intramolecular C—H⋯S interactions are obs...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977267/ https://www.ncbi.nlm.nih.gov/pubmed/21583444 http://dx.doi.org/10.1107/S1600536809024635 |
Sumario: | The title compound, C(15)H(12)N(2)OS(2), is an example of a push–pull butadiene in which the electron-releasing methylsulfanyl groups and electron-withdrawing nitrile groups on either end of the butadiene chain enhance the conjugation in the system. Short intramolecular C—H⋯S interactions are observed. In the crystal structure, an O⋯C short contact of 2.917 (3) Å is observed. |
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