2-[2-Benzoyl-3,3-bis­(methyl­sulfan­yl)prop-2-enyl­idene]malononitrile

The title compound, C(15)H(12)N(2)OS(2), is an example of a push–pull butadiene in which the electron-releasing methyl­sulfanyl groups and electron-withdrawing nitrile groups on either end of the butadiene chain enhance the conjugation in the system. Short intra­molecular C—H⋯S inter­actions are obs...

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Detalles Bibliográficos
Autores principales: Nirmala, Joseph, Unnikrishnan, N. V, Anabha, E. R, Sudarsanakumar, C.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977267/
https://www.ncbi.nlm.nih.gov/pubmed/21583444
http://dx.doi.org/10.1107/S1600536809024635
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author Nirmala, Joseph
Unnikrishnan, N. V
Anabha, E. R
Sudarsanakumar, C.
author_facet Nirmala, Joseph
Unnikrishnan, N. V
Anabha, E. R
Sudarsanakumar, C.
author_sort Nirmala, Joseph
collection PubMed
description The title compound, C(15)H(12)N(2)OS(2), is an example of a push–pull butadiene in which the electron-releasing methyl­sulfanyl groups and electron-withdrawing nitrile groups on either end of the butadiene chain enhance the conjugation in the system. Short intra­molecular C—H⋯S inter­actions are observed. In the crystal structure, an O⋯C short contact of 2.917 (3) Å is observed.
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spelling pubmed-29772672010-12-30 2-[2-Benzoyl-3,3-bis­(methyl­sulfan­yl)prop-2-enyl­idene]malononitrile Nirmala, Joseph Unnikrishnan, N. V Anabha, E. R Sudarsanakumar, C. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(15)H(12)N(2)OS(2), is an example of a push–pull butadiene in which the electron-releasing methyl­sulfanyl groups and electron-withdrawing nitrile groups on either end of the butadiene chain enhance the conjugation in the system. Short intra­molecular C—H⋯S inter­actions are observed. In the crystal structure, an O⋯C short contact of 2.917 (3) Å is observed. International Union of Crystallography 2009-07-01 /pmc/articles/PMC2977267/ /pubmed/21583444 http://dx.doi.org/10.1107/S1600536809024635 Text en © Nirmala et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Nirmala, Joseph
Unnikrishnan, N. V
Anabha, E. R
Sudarsanakumar, C.
2-[2-Benzoyl-3,3-bis­(methyl­sulfan­yl)prop-2-enyl­idene]malononitrile
title 2-[2-Benzoyl-3,3-bis­(methyl­sulfan­yl)prop-2-enyl­idene]malononitrile
title_full 2-[2-Benzoyl-3,3-bis­(methyl­sulfan­yl)prop-2-enyl­idene]malononitrile
title_fullStr 2-[2-Benzoyl-3,3-bis­(methyl­sulfan­yl)prop-2-enyl­idene]malononitrile
title_full_unstemmed 2-[2-Benzoyl-3,3-bis­(methyl­sulfan­yl)prop-2-enyl­idene]malononitrile
title_short 2-[2-Benzoyl-3,3-bis­(methyl­sulfan­yl)prop-2-enyl­idene]malononitrile
title_sort 2-[2-benzoyl-3,3-bis­(methyl­sulfan­yl)prop-2-enyl­idene]malononitrile
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977267/
https://www.ncbi.nlm.nih.gov/pubmed/21583444
http://dx.doi.org/10.1107/S1600536809024635
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