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catena-Poly[zinc(II)-μ-aqua-κ(2) O:O-bis(μ-quinoline-4-carboxylato-κ(2) O:O′)]
The asymmetric unit of the title complex, [Zn(C(10)H(6)NO(2))(2)(H(2)O)](n), consists of one quinoline-4-carboxylate anion, half of a Zn(2+) cation and half of a coordinated water molecule. The cation and the water O atom have crystallographically imposed inversion and twofold rotation symmetry, r...
Autores principales: | , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977275/ https://www.ncbi.nlm.nih.gov/pubmed/21583338 http://dx.doi.org/10.1107/S1600536809025392 |
Sumario: | The asymmetric unit of the title complex, [Zn(C(10)H(6)NO(2))(2)(H(2)O)](n), consists of one quinoline-4-carboxylate anion, half of a Zn(2+) cation and half of a coordinated water molecule. The cation and the water O atom have crystallographically imposed inversion and twofold rotation symmetry, respectively. The metal centre displays an elongated ZnO(6) octahedral coordination geometry provided by the O atoms of four anions at the equatorial plane and two axial water molecules. Each anion and water molecule act as bridges between Zn(II) cations, forming a polymeric chain parallel to [001]. The chains are further linked into a three-dimensional framework through O—H⋯N hydrogen bonds. |
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