Cargando…

catena-Poly[zinc(II)-μ-aqua-κ(2) O:O-bis­(μ-quinoline-4-carboxyl­ato-κ(2) O:O′)]

The asymmetric unit of the title complex, [Zn(C(10)H(6)NO(2))(2)(H(2)O)](n), consists of one quinoline-4-carboxyl­ate anion, half of a Zn(2+) cation and half of a coordinated water mol­ecule. The cation and the water O atom have crystallographically imposed inversion and twofold rotation symmetry, r...

Descripción completa

Detalles Bibliográficos
Autores principales: Chen, Jin-Xi, Meng, Wei-Wei
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977275/
https://www.ncbi.nlm.nih.gov/pubmed/21583338
http://dx.doi.org/10.1107/S1600536809025392
_version_ 1782191069092380672
author Chen, Jin-Xi
Meng, Wei-Wei
author_facet Chen, Jin-Xi
Meng, Wei-Wei
author_sort Chen, Jin-Xi
collection PubMed
description The asymmetric unit of the title complex, [Zn(C(10)H(6)NO(2))(2)(H(2)O)](n), consists of one quinoline-4-carboxyl­ate anion, half of a Zn(2+) cation and half of a coordinated water mol­ecule. The cation and the water O atom have crystallographically imposed inversion and twofold rotation symmetry, respectively. The metal centre displays an elongated ZnO(6) octa­hedral coordination geometry provided by the O atoms of four anions at the equatorial plane and two axial water mol­ecules. Each anion and water mol­ecule act as bridges between Zn(II) cations, forming a polymeric chain parallel to [001]. The chains are further linked into a three-dimensional framework through O—H⋯N hydrogen bonds.
format Text
id pubmed-2977275
institution National Center for Biotechnology Information
language English
publishDate 2009
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29772752010-12-30 catena-Poly[zinc(II)-μ-aqua-κ(2) O:O-bis­(μ-quinoline-4-carboxyl­ato-κ(2) O:O′)] Chen, Jin-Xi Meng, Wei-Wei Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title complex, [Zn(C(10)H(6)NO(2))(2)(H(2)O)](n), consists of one quinoline-4-carboxyl­ate anion, half of a Zn(2+) cation and half of a coordinated water mol­ecule. The cation and the water O atom have crystallographically imposed inversion and twofold rotation symmetry, respectively. The metal centre displays an elongated ZnO(6) octa­hedral coordination geometry provided by the O atoms of four anions at the equatorial plane and two axial water mol­ecules. Each anion and water mol­ecule act as bridges between Zn(II) cations, forming a polymeric chain parallel to [001]. The chains are further linked into a three-dimensional framework through O—H⋯N hydrogen bonds. International Union of Crystallography 2009-07-04 /pmc/articles/PMC2977275/ /pubmed/21583338 http://dx.doi.org/10.1107/S1600536809025392 Text en © Chen and Meng 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Chen, Jin-Xi
Meng, Wei-Wei
catena-Poly[zinc(II)-μ-aqua-κ(2) O:O-bis­(μ-quinoline-4-carboxyl­ato-κ(2) O:O′)]
title catena-Poly[zinc(II)-μ-aqua-κ(2) O:O-bis­(μ-quinoline-4-carboxyl­ato-κ(2) O:O′)]
title_full catena-Poly[zinc(II)-μ-aqua-κ(2) O:O-bis­(μ-quinoline-4-carboxyl­ato-κ(2) O:O′)]
title_fullStr catena-Poly[zinc(II)-μ-aqua-κ(2) O:O-bis­(μ-quinoline-4-carboxyl­ato-κ(2) O:O′)]
title_full_unstemmed catena-Poly[zinc(II)-μ-aqua-κ(2) O:O-bis­(μ-quinoline-4-carboxyl­ato-κ(2) O:O′)]
title_short catena-Poly[zinc(II)-μ-aqua-κ(2) O:O-bis­(μ-quinoline-4-carboxyl­ato-κ(2) O:O′)]
title_sort catena-poly[zinc(ii)-μ-aqua-κ(2) o:o-bis­(μ-quinoline-4-carboxyl­ato-κ(2) o:o′)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977275/
https://www.ncbi.nlm.nih.gov/pubmed/21583338
http://dx.doi.org/10.1107/S1600536809025392
work_keys_str_mv AT chenjinxi catenapolyzinciimaquak2oobismquinoline4carboxylatok2oo
AT mengweiwei catenapolyzinciimaquak2oobismquinoline4carboxylatok2oo