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catena-Poly[zinc(II)-μ-aqua-κ(2) O:O-bis(μ-quinoline-4-carboxylato-κ(2) O:O′)]
The asymmetric unit of the title complex, [Zn(C(10)H(6)NO(2))(2)(H(2)O)](n), consists of one quinoline-4-carboxylate anion, half of a Zn(2+) cation and half of a coordinated water molecule. The cation and the water O atom have crystallographically imposed inversion and twofold rotation symmetry, r...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977275/ https://www.ncbi.nlm.nih.gov/pubmed/21583338 http://dx.doi.org/10.1107/S1600536809025392 |
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author | Chen, Jin-Xi Meng, Wei-Wei |
author_facet | Chen, Jin-Xi Meng, Wei-Wei |
author_sort | Chen, Jin-Xi |
collection | PubMed |
description | The asymmetric unit of the title complex, [Zn(C(10)H(6)NO(2))(2)(H(2)O)](n), consists of one quinoline-4-carboxylate anion, half of a Zn(2+) cation and half of a coordinated water molecule. The cation and the water O atom have crystallographically imposed inversion and twofold rotation symmetry, respectively. The metal centre displays an elongated ZnO(6) octahedral coordination geometry provided by the O atoms of four anions at the equatorial plane and two axial water molecules. Each anion and water molecule act as bridges between Zn(II) cations, forming a polymeric chain parallel to [001]. The chains are further linked into a three-dimensional framework through O—H⋯N hydrogen bonds. |
format | Text |
id | pubmed-2977275 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29772752010-12-30 catena-Poly[zinc(II)-μ-aqua-κ(2) O:O-bis(μ-quinoline-4-carboxylato-κ(2) O:O′)] Chen, Jin-Xi Meng, Wei-Wei Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title complex, [Zn(C(10)H(6)NO(2))(2)(H(2)O)](n), consists of one quinoline-4-carboxylate anion, half of a Zn(2+) cation and half of a coordinated water molecule. The cation and the water O atom have crystallographically imposed inversion and twofold rotation symmetry, respectively. The metal centre displays an elongated ZnO(6) octahedral coordination geometry provided by the O atoms of four anions at the equatorial plane and two axial water molecules. Each anion and water molecule act as bridges between Zn(II) cations, forming a polymeric chain parallel to [001]. The chains are further linked into a three-dimensional framework through O—H⋯N hydrogen bonds. International Union of Crystallography 2009-07-04 /pmc/articles/PMC2977275/ /pubmed/21583338 http://dx.doi.org/10.1107/S1600536809025392 Text en © Chen and Meng 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Chen, Jin-Xi Meng, Wei-Wei catena-Poly[zinc(II)-μ-aqua-κ(2) O:O-bis(μ-quinoline-4-carboxylato-κ(2) O:O′)] |
title |
catena-Poly[zinc(II)-μ-aqua-κ(2)
O:O-bis(μ-quinoline-4-carboxylato-κ(2)
O:O′)] |
title_full |
catena-Poly[zinc(II)-μ-aqua-κ(2)
O:O-bis(μ-quinoline-4-carboxylato-κ(2)
O:O′)] |
title_fullStr |
catena-Poly[zinc(II)-μ-aqua-κ(2)
O:O-bis(μ-quinoline-4-carboxylato-κ(2)
O:O′)] |
title_full_unstemmed |
catena-Poly[zinc(II)-μ-aqua-κ(2)
O:O-bis(μ-quinoline-4-carboxylato-κ(2)
O:O′)] |
title_short |
catena-Poly[zinc(II)-μ-aqua-κ(2)
O:O-bis(μ-quinoline-4-carboxylato-κ(2)
O:O′)] |
title_sort | catena-poly[zinc(ii)-μ-aqua-κ(2)
o:o-bis(μ-quinoline-4-carboxylato-κ(2)
o:o′)] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977275/ https://www.ncbi.nlm.nih.gov/pubmed/21583338 http://dx.doi.org/10.1107/S1600536809025392 |
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