[μ-14,29-Di-tert-butyl-3,10,18,25-tetra­azatpenta­cyclo­[25.3.1.1(12,16).0(4,9).0(19,24)]dotriaconta-1(31),4,6,8,12(32),14,16,19,21,23,27,29-dodeca­ene-31,32-diol­ato]bis­[(nitrato-κ(2) O,O′)zinc(II)]

In the title centrosymmetric dinuclear zinc(II) complex, [Zn(2)(C(36)H(42)N(4)O(2))(NO(3))(2)], the Zn(II) atom has a distorted octa­hedral geometry, defined by two N atoms and two O atoms from the macrocyclic ligand and two O atoms from a chelating nitrate anion and are bridged by two phenolate O a...

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Detalles Bibliográficos
Autores principales: Fan, Li-Jing, Ma, Jian-Fang, Liu, Bo
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977276/
https://www.ncbi.nlm.nih.gov/pubmed/21583427
http://dx.doi.org/10.1107/S1600536809028530
Descripción
Sumario:In the title centrosymmetric dinuclear zinc(II) complex, [Zn(2)(C(36)H(42)N(4)O(2))(NO(3))(2)], the Zn(II) atom has a distorted octa­hedral geometry, defined by two N atoms and two O atoms from the macrocyclic ligand and two O atoms from a chelating nitrate anion and are bridged by two phenolate O atoms, forming a four-membered Zn(2)O(2) ring.

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