[μ-14,29-Di-tert-butyl-3,10,18,25-tetra­azatpenta­cyclo­[25.3.1.1(12,16).0(4,9).0(19,24)]dotriaconta-1(31),4,6,8,12(32),14,16,19,21,23,27,29-dodeca­ene-31,32-diol­ato]bis­[(nitrato-κ(2) O,O′)zinc(II)]

In the title centrosymmetric dinuclear zinc(II) complex, [Zn(2)(C(36)H(42)N(4)O(2))(NO(3))(2)], the Zn(II) atom has a distorted octa­hedral geometry, defined by two N atoms and two O atoms from the macrocyclic ligand and two O atoms from a chelating nitrate anion and are bridged by two phenolate O a...

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Detalles Bibliográficos
Autores principales: Fan, Li-Jing, Ma, Jian-Fang, Liu, Bo
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977276/
https://www.ncbi.nlm.nih.gov/pubmed/21583427
http://dx.doi.org/10.1107/S1600536809028530
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author Fan, Li-Jing
Ma, Jian-Fang
Liu, Bo
author_facet Fan, Li-Jing
Ma, Jian-Fang
Liu, Bo
author_sort Fan, Li-Jing
collection PubMed
description In the title centrosymmetric dinuclear zinc(II) complex, [Zn(2)(C(36)H(42)N(4)O(2))(NO(3))(2)], the Zn(II) atom has a distorted octa­hedral geometry, defined by two N atoms and two O atoms from the macrocyclic ligand and two O atoms from a chelating nitrate anion and are bridged by two phenolate O atoms, forming a four-membered Zn(2)O(2) ring.
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spelling pubmed-29772762010-12-30 [μ-14,29-Di-tert-butyl-3,10,18,25-tetra­azatpenta­cyclo­[25.3.1.1(12,16).0(4,9).0(19,24)]dotriaconta-1(31),4,6,8,12(32),14,16,19,21,23,27,29-dodeca­ene-31,32-diol­ato]bis­[(nitrato-κ(2) O,O′)zinc(II)] Fan, Li-Jing Ma, Jian-Fang Liu, Bo Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title centrosymmetric dinuclear zinc(II) complex, [Zn(2)(C(36)H(42)N(4)O(2))(NO(3))(2)], the Zn(II) atom has a distorted octa­hedral geometry, defined by two N atoms and two O atoms from the macrocyclic ligand and two O atoms from a chelating nitrate anion and are bridged by two phenolate O atoms, forming a four-membered Zn(2)O(2) ring. International Union of Crystallography 2009-07-25 /pmc/articles/PMC2977276/ /pubmed/21583427 http://dx.doi.org/10.1107/S1600536809028530 Text en © Fan et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Fan, Li-Jing
Ma, Jian-Fang
Liu, Bo
[μ-14,29-Di-tert-butyl-3,10,18,25-tetra­azatpenta­cyclo­[25.3.1.1(12,16).0(4,9).0(19,24)]dotriaconta-1(31),4,6,8,12(32),14,16,19,21,23,27,29-dodeca­ene-31,32-diol­ato]bis­[(nitrato-κ(2) O,O′)zinc(II)]
title [μ-14,29-Di-tert-butyl-3,10,18,25-tetra­azatpenta­cyclo­[25.3.1.1(12,16).0(4,9).0(19,24)]dotriaconta-1(31),4,6,8,12(32),14,16,19,21,23,27,29-dodeca­ene-31,32-diol­ato]bis­[(nitrato-κ(2) O,O′)zinc(II)]
title_full [μ-14,29-Di-tert-butyl-3,10,18,25-tetra­azatpenta­cyclo­[25.3.1.1(12,16).0(4,9).0(19,24)]dotriaconta-1(31),4,6,8,12(32),14,16,19,21,23,27,29-dodeca­ene-31,32-diol­ato]bis­[(nitrato-κ(2) O,O′)zinc(II)]
title_fullStr [μ-14,29-Di-tert-butyl-3,10,18,25-tetra­azatpenta­cyclo­[25.3.1.1(12,16).0(4,9).0(19,24)]dotriaconta-1(31),4,6,8,12(32),14,16,19,21,23,27,29-dodeca­ene-31,32-diol­ato]bis­[(nitrato-κ(2) O,O′)zinc(II)]
title_full_unstemmed [μ-14,29-Di-tert-butyl-3,10,18,25-tetra­azatpenta­cyclo­[25.3.1.1(12,16).0(4,9).0(19,24)]dotriaconta-1(31),4,6,8,12(32),14,16,19,21,23,27,29-dodeca­ene-31,32-diol­ato]bis­[(nitrato-κ(2) O,O′)zinc(II)]
title_short [μ-14,29-Di-tert-butyl-3,10,18,25-tetra­azatpenta­cyclo­[25.3.1.1(12,16).0(4,9).0(19,24)]dotriaconta-1(31),4,6,8,12(32),14,16,19,21,23,27,29-dodeca­ene-31,32-diol­ato]bis­[(nitrato-κ(2) O,O′)zinc(II)]
title_sort [μ-14,29-di-tert-butyl-3,10,18,25-tetra­azatpenta­cyclo­[25.3.1.1(12,16).0(4,9).0(19,24)]dotriaconta-1(31),4,6,8,12(32),14,16,19,21,23,27,29-dodeca­ene-31,32-diol­ato]bis­[(nitrato-κ(2) o,o′)zinc(ii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977276/
https://www.ncbi.nlm.nih.gov/pubmed/21583427
http://dx.doi.org/10.1107/S1600536809028530
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