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N-(4-tert-Butyl­benz­yl)phthalimide

The mol­ecule of the title compound [systematic name: 2-(4-tert-butyl­benz­yl)isoindoline-1,3-dione], C(19)H(19)NO(2), is V-shaped with a dihedral angle of 74.15 (7)° between the mean planes of the phthalimide unit and the benzene ring. The methyl groups of the tert-butyl substituent are disordered...

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Detalles Bibliográficos
Autores principales: Li, Jiang-Sheng, Simpson, Jim, Li, Xun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977282/
https://www.ncbi.nlm.nih.gov/pubmed/21583486
http://dx.doi.org/10.1107/S1600536809025343
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author Li, Jiang-Sheng
Simpson, Jim
Li, Xun
author_facet Li, Jiang-Sheng
Simpson, Jim
Li, Xun
author_sort Li, Jiang-Sheng
collection PubMed
description The mol­ecule of the title compound [systematic name: 2-(4-tert-butyl­benz­yl)isoindoline-1,3-dione], C(19)H(19)NO(2), is V-shaped with a dihedral angle of 74.15 (7)° between the mean planes of the phthalimide unit and the benzene ring. The methyl groups of the tert-butyl substituent are disordered over two sets of positions, with an occupancy ratio of 0.700 (4):0.300 (4). In the crystal, inter­molecular C—H⋯O hydrogen bonds link adjacent mol­ecules into centrosymmetric dimers. An additional weak C—H⋯O contact, together with weak C—H⋯π and π–π inter­actions [centroid–centroid distance = 3.961 (2) Å] generate a three-dimensional network.
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spelling pubmed-29772822010-12-30 N-(4-tert-Butyl­benz­yl)phthalimide Li, Jiang-Sheng Simpson, Jim Li, Xun Acta Crystallogr Sect E Struct Rep Online Organic Papers The mol­ecule of the title compound [systematic name: 2-(4-tert-butyl­benz­yl)isoindoline-1,3-dione], C(19)H(19)NO(2), is V-shaped with a dihedral angle of 74.15 (7)° between the mean planes of the phthalimide unit and the benzene ring. The methyl groups of the tert-butyl substituent are disordered over two sets of positions, with an occupancy ratio of 0.700 (4):0.300 (4). In the crystal, inter­molecular C—H⋯O hydrogen bonds link adjacent mol­ecules into centrosymmetric dimers. An additional weak C—H⋯O contact, together with weak C—H⋯π and π–π inter­actions [centroid–centroid distance = 3.961 (2) Å] generate a three-dimensional network. International Union of Crystallography 2009-07-04 /pmc/articles/PMC2977282/ /pubmed/21583486 http://dx.doi.org/10.1107/S1600536809025343 Text en © Li et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Li, Jiang-Sheng
Simpson, Jim
Li, Xun
N-(4-tert-Butyl­benz­yl)phthalimide
title N-(4-tert-Butyl­benz­yl)phthalimide
title_full N-(4-tert-Butyl­benz­yl)phthalimide
title_fullStr N-(4-tert-Butyl­benz­yl)phthalimide
title_full_unstemmed N-(4-tert-Butyl­benz­yl)phthalimide
title_short N-(4-tert-Butyl­benz­yl)phthalimide
title_sort n-(4-tert-butyl­benz­yl)phthalimide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977282/
https://www.ncbi.nlm.nih.gov/pubmed/21583486
http://dx.doi.org/10.1107/S1600536809025343
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