4-(4-Chloro­phen­yl)-6-(methyl­sulfan­yl)pyrimidin-2-amine

In the title compound, C(11)H(10)ClN(3)S, the dihedral angle between the benzene and pyrimidine rings is 3.99 (4)°. In the crystal, inter­molecular N—H⋯N hydrogen bonds link the mol­ecules into ribbons of R (2) (2)(8) rings parallel to [100]. Weak C—H⋯S contacts connect adjacent ribbons into a two-d...

Descripción completa

Detalles Bibliográficos
Autores principales: Zhao, Qi-Hua, Li, Li-Nan, Wang, Kun-Miao
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977289/
https://www.ncbi.nlm.nih.gov/pubmed/21583499
http://dx.doi.org/10.1107/S1600536809024891
Descripción
Sumario:In the title compound, C(11)H(10)ClN(3)S, the dihedral angle between the benzene and pyrimidine rings is 3.99 (4)°. In the crystal, inter­molecular N—H⋯N hydrogen bonds link the mol­ecules into ribbons of R (2) (2)(8) rings parallel to [100]. Weak C—H⋯S contacts connect adjacent ribbons into a two-dimensional undulating layer-like structure extending parallel to (110). The benzene and pyrimidine rings of adjacent mol­ecules have the offset face-to-face π–π stacking inter­actions in a zigzag fashion along the c axis, with perpendicular ring distances of 3.463 and 3.639 Å, and a dihedral angle between the planes of 3.99 (2)°. The distance between the ring centroids is 4.420 (2) Å.

Ejemplares similares