4-(4-Chloro­phen­yl)-6-(methyl­sulfan­yl)pyrimidin-2-amine

In the title compound, C(11)H(10)ClN(3)S, the dihedral angle between the benzene and pyrimidine rings is 3.99 (4)°. In the crystal, inter­molecular N—H⋯N hydrogen bonds link the mol­ecules into ribbons of R (2) (2)(8) rings parallel to [100]. Weak C—H⋯S contacts connect adjacent ribbons into a two-d...

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Detalles Bibliográficos
Autores principales: Zhao, Qi-Hua, Li, Li-Nan, Wang, Kun-Miao
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977289/
https://www.ncbi.nlm.nih.gov/pubmed/21583499
http://dx.doi.org/10.1107/S1600536809024891
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author Zhao, Qi-Hua
Li, Li-Nan
Wang, Kun-Miao
author_facet Zhao, Qi-Hua
Li, Li-Nan
Wang, Kun-Miao
author_sort Zhao, Qi-Hua
collection PubMed
description In the title compound, C(11)H(10)ClN(3)S, the dihedral angle between the benzene and pyrimidine rings is 3.99 (4)°. In the crystal, inter­molecular N—H⋯N hydrogen bonds link the mol­ecules into ribbons of R (2) (2)(8) rings parallel to [100]. Weak C—H⋯S contacts connect adjacent ribbons into a two-dimensional undulating layer-like structure extending parallel to (110). The benzene and pyrimidine rings of adjacent mol­ecules have the offset face-to-face π–π stacking inter­actions in a zigzag fashion along the c axis, with perpendicular ring distances of 3.463 and 3.639 Å, and a dihedral angle between the planes of 3.99 (2)°. The distance between the ring centroids is 4.420 (2) Å.
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spelling pubmed-29772892010-12-30 4-(4-Chloro­phen­yl)-6-(methyl­sulfan­yl)pyrimidin-2-amine Zhao, Qi-Hua Li, Li-Nan Wang, Kun-Miao Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(11)H(10)ClN(3)S, the dihedral angle between the benzene and pyrimidine rings is 3.99 (4)°. In the crystal, inter­molecular N—H⋯N hydrogen bonds link the mol­ecules into ribbons of R (2) (2)(8) rings parallel to [100]. Weak C—H⋯S contacts connect adjacent ribbons into a two-dimensional undulating layer-like structure extending parallel to (110). The benzene and pyrimidine rings of adjacent mol­ecules have the offset face-to-face π–π stacking inter­actions in a zigzag fashion along the c axis, with perpendicular ring distances of 3.463 and 3.639 Å, and a dihedral angle between the planes of 3.99 (2)°. The distance between the ring centroids is 4.420 (2) Å. International Union of Crystallography 2009-07-08 /pmc/articles/PMC2977289/ /pubmed/21583499 http://dx.doi.org/10.1107/S1600536809024891 Text en © Zhao et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Zhao, Qi-Hua
Li, Li-Nan
Wang, Kun-Miao
4-(4-Chloro­phen­yl)-6-(methyl­sulfan­yl)pyrimidin-2-amine
title 4-(4-Chloro­phen­yl)-6-(methyl­sulfan­yl)pyrimidin-2-amine
title_full 4-(4-Chloro­phen­yl)-6-(methyl­sulfan­yl)pyrimidin-2-amine
title_fullStr 4-(4-Chloro­phen­yl)-6-(methyl­sulfan­yl)pyrimidin-2-amine
title_full_unstemmed 4-(4-Chloro­phen­yl)-6-(methyl­sulfan­yl)pyrimidin-2-amine
title_short 4-(4-Chloro­phen­yl)-6-(methyl­sulfan­yl)pyrimidin-2-amine
title_sort 4-(4-chloro­phen­yl)-6-(methyl­sulfan­yl)pyrimidin-2-amine
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977289/
https://www.ncbi.nlm.nih.gov/pubmed/21583499
http://dx.doi.org/10.1107/S1600536809024891
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