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Poly[[μ-1,4-bis(imidazol-1-ylmethyl)benzene]bis(μ(4)-cyclohexane-1,4-dicarboxylato)dinickel(II)]
The structure of the polymeric title compound, [Ni(2)(C(8)H(10)O(4))(2)(C(14)H(14)N(4))](n), features a five-coordinate Ni(II) centre defined by four carboxylate O atoms from two different cyclohexane-1,4-dicarboxylate (chdc) ligands and an N atom from one end of a 1,4-bis(imidazol-1-ylmethyl)b...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977293/ https://www.ncbi.nlm.nih.gov/pubmed/21583309 http://dx.doi.org/10.1107/S1600536809029249 |
Sumario: | The structure of the polymeric title compound, [Ni(2)(C(8)H(10)O(4))(2)(C(14)H(14)N(4))](n), features a five-coordinate Ni(II) centre defined by four carboxylate O atoms from two different cyclohexane-1,4-dicarboxylate (chdc) ligands and an N atom from one end of a 1,4-bis(imidazol-1-ylmethyl)benzene (1,4-bix) molecule. The NO(4) coordination geometry is distorted square-pyramidal with the N atom in the apical position. Each end of the chdc ligand links pairs of Ni(II) atoms into a paddle-wheel assembly, i.e. Ni(2)(O(2)CR′)(4). These are connected into rows owing to the bridging nature of the chdc ligands, and the rows are connected into a two-dimensional grid via the 1,4-bix ligands. The 1,4-bix ligand, which is disposed about a centre of inversion, is disorderd. Two positions of equal occupancy were discerned for the –H(2)C(C(6)H(4))CH(2)– residue. |
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