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Poly[[μ-1,4-bis­(imidazol-1-ylmeth­yl)benzene]bis­(μ(4)-cyclo­hexane-1,4-dicarboxyl­ato)dinickel(II)]

The structure of the polymeric title compound, [Ni(2)(C(8)H(10)O(4))(2)(C(14)H(14)N(4))](n), features a five-coordinate Ni(II) centre defined by four carboxyl­ate O atoms from two different cyclo­hexane-1,4-dicarboxyl­ate (chdc) ligands and an N atom from one end of a 1,4-bis­(imidazol-1-ylmeth­yl)b...

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Autores principales: Li, Bing-Bing, Fang, Gai-Xia, Ji, Xiao-Na, Xiao, Bo, Tiekink, Edward R. T.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977293/
https://www.ncbi.nlm.nih.gov/pubmed/21583309
http://dx.doi.org/10.1107/S1600536809029249
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author Li, Bing-Bing
Fang, Gai-Xia
Ji, Xiao-Na
Xiao, Bo
Tiekink, Edward R. T.
author_facet Li, Bing-Bing
Fang, Gai-Xia
Ji, Xiao-Na
Xiao, Bo
Tiekink, Edward R. T.
author_sort Li, Bing-Bing
collection PubMed
description The structure of the polymeric title compound, [Ni(2)(C(8)H(10)O(4))(2)(C(14)H(14)N(4))](n), features a five-coordinate Ni(II) centre defined by four carboxyl­ate O atoms from two different cyclo­hexane-1,4-dicarboxyl­ate (chdc) ligands and an N atom from one end of a 1,4-bis­(imidazol-1-ylmeth­yl)benzene (1,4-bix) mol­ecule. The NO(4) coordination geometry is distorted square-pyramidal with the N atom in the apical position. Each end of the chdc ligand links pairs of Ni(II) atoms into a paddle-wheel assembly, i.e. Ni(2)(O(2)CR′)(4). These are connected into rows owing to the bridging nature of the chdc ligands, and the rows are connected into a two-dimensional grid via the 1,4-bix ligands. The 1,4-bix ligand, which is disposed about a centre of inversion, is disorderd. Two positions of equal occupancy were discerned for the –H(2)C(C(6)H(4))CH(2)– residue.
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spelling pubmed-29772932010-12-30 Poly[[μ-1,4-bis­(imidazol-1-ylmeth­yl)benzene]bis­(μ(4)-cyclo­hexane-1,4-dicarboxyl­ato)dinickel(II)] Li, Bing-Bing Fang, Gai-Xia Ji, Xiao-Na Xiao, Bo Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The structure of the polymeric title compound, [Ni(2)(C(8)H(10)O(4))(2)(C(14)H(14)N(4))](n), features a five-coordinate Ni(II) centre defined by four carboxyl­ate O atoms from two different cyclo­hexane-1,4-dicarboxyl­ate (chdc) ligands and an N atom from one end of a 1,4-bis­(imidazol-1-ylmeth­yl)benzene (1,4-bix) mol­ecule. The NO(4) coordination geometry is distorted square-pyramidal with the N atom in the apical position. Each end of the chdc ligand links pairs of Ni(II) atoms into a paddle-wheel assembly, i.e. Ni(2)(O(2)CR′)(4). These are connected into rows owing to the bridging nature of the chdc ligands, and the rows are connected into a two-dimensional grid via the 1,4-bix ligands. The 1,4-bix ligand, which is disposed about a centre of inversion, is disorderd. Two positions of equal occupancy were discerned for the –H(2)C(C(6)H(4))CH(2)– residue. International Union of Crystallography 2009-07-31 /pmc/articles/PMC2977293/ /pubmed/21583309 http://dx.doi.org/10.1107/S1600536809029249 Text en © Li et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Li, Bing-Bing
Fang, Gai-Xia
Ji, Xiao-Na
Xiao, Bo
Tiekink, Edward R. T.
Poly[[μ-1,4-bis­(imidazol-1-ylmeth­yl)benzene]bis­(μ(4)-cyclo­hexane-1,4-dicarboxyl­ato)dinickel(II)]
title Poly[[μ-1,4-bis­(imidazol-1-ylmeth­yl)benzene]bis­(μ(4)-cyclo­hexane-1,4-dicarboxyl­ato)dinickel(II)]
title_full Poly[[μ-1,4-bis­(imidazol-1-ylmeth­yl)benzene]bis­(μ(4)-cyclo­hexane-1,4-dicarboxyl­ato)dinickel(II)]
title_fullStr Poly[[μ-1,4-bis­(imidazol-1-ylmeth­yl)benzene]bis­(μ(4)-cyclo­hexane-1,4-dicarboxyl­ato)dinickel(II)]
title_full_unstemmed Poly[[μ-1,4-bis­(imidazol-1-ylmeth­yl)benzene]bis­(μ(4)-cyclo­hexane-1,4-dicarboxyl­ato)dinickel(II)]
title_short Poly[[μ-1,4-bis­(imidazol-1-ylmeth­yl)benzene]bis­(μ(4)-cyclo­hexane-1,4-dicarboxyl­ato)dinickel(II)]
title_sort poly[[μ-1,4-bis­(imidazol-1-ylmeth­yl)benzene]bis­(μ(4)-cyclo­hexane-1,4-dicarboxyl­ato)dinickel(ii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977293/
https://www.ncbi.nlm.nih.gov/pubmed/21583309
http://dx.doi.org/10.1107/S1600536809029249
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