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Poly[[μ-1,4-bis(imidazol-1-ylmethyl)benzene]bis(μ(4)-cyclohexane-1,4-dicarboxylato)dinickel(II)]
The structure of the polymeric title compound, [Ni(2)(C(8)H(10)O(4))(2)(C(14)H(14)N(4))](n), features a five-coordinate Ni(II) centre defined by four carboxylate O atoms from two different cyclohexane-1,4-dicarboxylate (chdc) ligands and an N atom from one end of a 1,4-bis(imidazol-1-ylmethyl)b...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2009
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977293/ https://www.ncbi.nlm.nih.gov/pubmed/21583309 http://dx.doi.org/10.1107/S1600536809029249 |
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author | Li, Bing-Bing Fang, Gai-Xia Ji, Xiao-Na Xiao, Bo Tiekink, Edward R. T. |
author_facet | Li, Bing-Bing Fang, Gai-Xia Ji, Xiao-Na Xiao, Bo Tiekink, Edward R. T. |
author_sort | Li, Bing-Bing |
collection | PubMed |
description | The structure of the polymeric title compound, [Ni(2)(C(8)H(10)O(4))(2)(C(14)H(14)N(4))](n), features a five-coordinate Ni(II) centre defined by four carboxylate O atoms from two different cyclohexane-1,4-dicarboxylate (chdc) ligands and an N atom from one end of a 1,4-bis(imidazol-1-ylmethyl)benzene (1,4-bix) molecule. The NO(4) coordination geometry is distorted square-pyramidal with the N atom in the apical position. Each end of the chdc ligand links pairs of Ni(II) atoms into a paddle-wheel assembly, i.e. Ni(2)(O(2)CR′)(4). These are connected into rows owing to the bridging nature of the chdc ligands, and the rows are connected into a two-dimensional grid via the 1,4-bix ligands. The 1,4-bix ligand, which is disposed about a centre of inversion, is disorderd. Two positions of equal occupancy were discerned for the –H(2)C(C(6)H(4))CH(2)– residue. |
format | Text |
id | pubmed-2977293 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29772932010-12-30 Poly[[μ-1,4-bis(imidazol-1-ylmethyl)benzene]bis(μ(4)-cyclohexane-1,4-dicarboxylato)dinickel(II)] Li, Bing-Bing Fang, Gai-Xia Ji, Xiao-Na Xiao, Bo Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The structure of the polymeric title compound, [Ni(2)(C(8)H(10)O(4))(2)(C(14)H(14)N(4))](n), features a five-coordinate Ni(II) centre defined by four carboxylate O atoms from two different cyclohexane-1,4-dicarboxylate (chdc) ligands and an N atom from one end of a 1,4-bis(imidazol-1-ylmethyl)benzene (1,4-bix) molecule. The NO(4) coordination geometry is distorted square-pyramidal with the N atom in the apical position. Each end of the chdc ligand links pairs of Ni(II) atoms into a paddle-wheel assembly, i.e. Ni(2)(O(2)CR′)(4). These are connected into rows owing to the bridging nature of the chdc ligands, and the rows are connected into a two-dimensional grid via the 1,4-bix ligands. The 1,4-bix ligand, which is disposed about a centre of inversion, is disorderd. Two positions of equal occupancy were discerned for the –H(2)C(C(6)H(4))CH(2)– residue. International Union of Crystallography 2009-07-31 /pmc/articles/PMC2977293/ /pubmed/21583309 http://dx.doi.org/10.1107/S1600536809029249 Text en © Li et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Li, Bing-Bing Fang, Gai-Xia Ji, Xiao-Na Xiao, Bo Tiekink, Edward R. T. Poly[[μ-1,4-bis(imidazol-1-ylmethyl)benzene]bis(μ(4)-cyclohexane-1,4-dicarboxylato)dinickel(II)] |
title | Poly[[μ-1,4-bis(imidazol-1-ylmethyl)benzene]bis(μ(4)-cyclohexane-1,4-dicarboxylato)dinickel(II)] |
title_full | Poly[[μ-1,4-bis(imidazol-1-ylmethyl)benzene]bis(μ(4)-cyclohexane-1,4-dicarboxylato)dinickel(II)] |
title_fullStr | Poly[[μ-1,4-bis(imidazol-1-ylmethyl)benzene]bis(μ(4)-cyclohexane-1,4-dicarboxylato)dinickel(II)] |
title_full_unstemmed | Poly[[μ-1,4-bis(imidazol-1-ylmethyl)benzene]bis(μ(4)-cyclohexane-1,4-dicarboxylato)dinickel(II)] |
title_short | Poly[[μ-1,4-bis(imidazol-1-ylmethyl)benzene]bis(μ(4)-cyclohexane-1,4-dicarboxylato)dinickel(II)] |
title_sort | poly[[μ-1,4-bis(imidazol-1-ylmethyl)benzene]bis(μ(4)-cyclohexane-1,4-dicarboxylato)dinickel(ii)] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977293/ https://www.ncbi.nlm.nih.gov/pubmed/21583309 http://dx.doi.org/10.1107/S1600536809029249 |
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