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Bis(1H-imidazole-κN (3))bis(2-oxidopyridinium-3-carboxylato-κ(2) O (2),O (3))cobalt(II)
In the molecule of the title Co(II) complex, [Co(C(6)H(4)NO(3))(2)(C(3)H(4)N(2))(2)], the Co(II) atom is located on a twofold rotation axis and chelated by two oxidopyridiniumcarboxylate anions and further cis-coordinated by two imidazole ligands in a distorted octahedral geometry. The shorter C—...
| Autores principales: | , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2009
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977295/ https://www.ncbi.nlm.nih.gov/pubmed/21583429 http://dx.doi.org/10.1107/S1600536809028694 |
| _version_ | 1782191073871790080 |
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| author | Zhang, Bing-Yu Nie, Jing-Jing Xu, Duan-Jun |
| author_facet | Zhang, Bing-Yu Nie, Jing-Jing Xu, Duan-Jun |
| author_sort | Zhang, Bing-Yu |
| collection | PubMed |
| description | In the molecule of the title Co(II) complex, [Co(C(6)H(4)NO(3))(2)(C(3)H(4)N(2))(2)], the Co(II) atom is located on a twofold rotation axis and chelated by two oxidopyridiniumcarboxylate anions and further cis-coordinated by two imidazole ligands in a distorted octahedral geometry. The shorter C—O bond distance of 1.260 (2) Å suggests electron delocalization between the oxido group and the pyridinium ring. The uncoordinated carboxylate O atom links with the imidazole and pyridinium rings of adjacent molecules via N—H⋯O hydrogen bonding. Weak C—H⋯O hydrogen bonding is also present in the crystal structure. |
| format | Text |
| id | pubmed-2977295 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2009 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29772952010-12-30 Bis(1H-imidazole-κN (3))bis(2-oxidopyridinium-3-carboxylato-κ(2) O (2),O (3))cobalt(II) Zhang, Bing-Yu Nie, Jing-Jing Xu, Duan-Jun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the molecule of the title Co(II) complex, [Co(C(6)H(4)NO(3))(2)(C(3)H(4)N(2))(2)], the Co(II) atom is located on a twofold rotation axis and chelated by two oxidopyridiniumcarboxylate anions and further cis-coordinated by two imidazole ligands in a distorted octahedral geometry. The shorter C—O bond distance of 1.260 (2) Å suggests electron delocalization between the oxido group and the pyridinium ring. The uncoordinated carboxylate O atom links with the imidazole and pyridinium rings of adjacent molecules via N—H⋯O hydrogen bonding. Weak C—H⋯O hydrogen bonding is also present in the crystal structure. International Union of Crystallography 2009-07-25 /pmc/articles/PMC2977295/ /pubmed/21583429 http://dx.doi.org/10.1107/S1600536809028694 Text en © Zhang et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Zhang, Bing-Yu Nie, Jing-Jing Xu, Duan-Jun Bis(1H-imidazole-κN (3))bis(2-oxidopyridinium-3-carboxylato-κ(2) O (2),O (3))cobalt(II) |
| title | Bis(1H-imidazole-κN
(3))bis(2-oxidopyridinium-3-carboxylato-κ(2)
O
(2),O
(3))cobalt(II) |
| title_full | Bis(1H-imidazole-κN
(3))bis(2-oxidopyridinium-3-carboxylato-κ(2)
O
(2),O
(3))cobalt(II) |
| title_fullStr | Bis(1H-imidazole-κN
(3))bis(2-oxidopyridinium-3-carboxylato-κ(2)
O
(2),O
(3))cobalt(II) |
| title_full_unstemmed | Bis(1H-imidazole-κN
(3))bis(2-oxidopyridinium-3-carboxylato-κ(2)
O
(2),O
(3))cobalt(II) |
| title_short | Bis(1H-imidazole-κN
(3))bis(2-oxidopyridinium-3-carboxylato-κ(2)
O
(2),O
(3))cobalt(II) |
| title_sort | bis(1h-imidazole-κn
(3))bis(2-oxidopyridinium-3-carboxylato-κ(2)
o
(2),o
(3))cobalt(ii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977295/ https://www.ncbi.nlm.nih.gov/pubmed/21583429 http://dx.doi.org/10.1107/S1600536809028694 |
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