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Tetra-μ(2)-acetato-bis{μ(2)-5-methoxy-2-[(2-morpholinoethyl)iminiomethyl]phenolato}tricadmium(II)
The central Cd(II) atom in the trinuclear title compound, [Cd(3)(C(14)H(19)N(2)O(3))(2)(CH(3)COO)(4)], lies on a center of inversion and is bonded to the O atoms of four acetate groups as well as to the phenolate O atoms of the mono-deprotonated Schiff base ligands in a distorted all-trans octahedr...
| Autores principales: | , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2009
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977297/ https://www.ncbi.nlm.nih.gov/pubmed/21583308 http://dx.doi.org/10.1107/S1600536809029171 |
| _version_ | 1782191074336309248 |
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| author | Mohd Lair, Nooraziah Mohd Ali, Hapipah Ng, Seik Weng |
| author_facet | Mohd Lair, Nooraziah Mohd Ali, Hapipah Ng, Seik Weng |
| author_sort | Mohd Lair, Nooraziah |
| collection | PubMed |
| description | The central Cd(II) atom in the trinuclear title compound, [Cd(3)(C(14)H(19)N(2)O(3))(2)(CH(3)COO)(4)], lies on a center of inversion and is bonded to the O atoms of four acetate groups as well as to the phenolate O atoms of the mono-deprotonated Schiff base ligands in a distorted all-trans octahedral geometry. Two of the acetate groups function in a μ(2)-bridging mode, while the other two each chelate to the terminal Cd(II) atom and simultaneously bind to the central metal atom in a κ(3)-bonding mode. The Schiff base anions N,O-chelate to the terminal metal atoms. The morpholine ring assumes a chair conformation. |
| format | Text |
| id | pubmed-2977297 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2009 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29772972010-12-30 Tetra-μ(2)-acetato-bis{μ(2)-5-methoxy-2-[(2-morpholinoethyl)iminiomethyl]phenolato}tricadmium(II) Mohd Lair, Nooraziah Mohd Ali, Hapipah Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The central Cd(II) atom in the trinuclear title compound, [Cd(3)(C(14)H(19)N(2)O(3))(2)(CH(3)COO)(4)], lies on a center of inversion and is bonded to the O atoms of four acetate groups as well as to the phenolate O atoms of the mono-deprotonated Schiff base ligands in a distorted all-trans octahedral geometry. Two of the acetate groups function in a μ(2)-bridging mode, while the other two each chelate to the terminal Cd(II) atom and simultaneously bind to the central metal atom in a κ(3)-bonding mode. The Schiff base anions N,O-chelate to the terminal metal atoms. The morpholine ring assumes a chair conformation. International Union of Crystallography 2009-07-31 /pmc/articles/PMC2977297/ /pubmed/21583308 http://dx.doi.org/10.1107/S1600536809029171 Text en © Mohd Lair et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Mohd Lair, Nooraziah Mohd Ali, Hapipah Ng, Seik Weng Tetra-μ(2)-acetato-bis{μ(2)-5-methoxy-2-[(2-morpholinoethyl)iminiomethyl]phenolato}tricadmium(II) |
| title | Tetra-μ(2)-acetato-bis{μ(2)-5-methoxy-2-[(2-morpholinoethyl)iminiomethyl]phenolato}tricadmium(II) |
| title_full | Tetra-μ(2)-acetato-bis{μ(2)-5-methoxy-2-[(2-morpholinoethyl)iminiomethyl]phenolato}tricadmium(II) |
| title_fullStr | Tetra-μ(2)-acetato-bis{μ(2)-5-methoxy-2-[(2-morpholinoethyl)iminiomethyl]phenolato}tricadmium(II) |
| title_full_unstemmed | Tetra-μ(2)-acetato-bis{μ(2)-5-methoxy-2-[(2-morpholinoethyl)iminiomethyl]phenolato}tricadmium(II) |
| title_short | Tetra-μ(2)-acetato-bis{μ(2)-5-methoxy-2-[(2-morpholinoethyl)iminiomethyl]phenolato}tricadmium(II) |
| title_sort | tetra-μ(2)-acetato-bis{μ(2)-5-methoxy-2-[(2-morpholinoethyl)iminiomethyl]phenolato}tricadmium(ii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977297/ https://www.ncbi.nlm.nih.gov/pubmed/21583308 http://dx.doi.org/10.1107/S1600536809029171 |
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