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2-Acetamido-2-deoxy-3-O-β-d-galactopyranosyl-d-glucose dihydrate
In the title compound, C(14)H(25)NO(11)·2H(2)O, the primary hydroxyl group connected to the anomeric C atom of the N-acetyl-β-d-glucopyranose residue exhibits positional disorder, with occupancy factors for the α and β anomers of 0.77 and 0.23, respectively. The two torsion angles (Φ and Ψ) and the...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977301/ https://www.ncbi.nlm.nih.gov/pubmed/21583488 http://dx.doi.org/10.1107/S1600536809024775 |
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author | Wada, Masahisa Kobayashi, Kayoko Nishimoto, Mamoru Kitaoka, Motomitsu Noguchi, Keiichi |
author_facet | Wada, Masahisa Kobayashi, Kayoko Nishimoto, Mamoru Kitaoka, Motomitsu Noguchi, Keiichi |
author_sort | Wada, Masahisa |
collection | PubMed |
description | In the title compound, C(14)H(25)NO(11)·2H(2)O, the primary hydroxyl group connected to the anomeric C atom of the N-acetyl-β-d-glucopyranose residue exhibits positional disorder, with occupancy factors for the α and β anomers of 0.77 and 0.23, respectively. The two torsion angles (Φ and Ψ) and the bridge angle (τ) that describe conformation of the glycosidic linkage between the galactopyranose and glucopyranose rings are Φ = −81.6 (3)°, Ψ = 118.1 (2)° and τ = 115.2 (2)°. Two water molecules stabilize the molecular packing by forming hydrogen bonds with the saccharide residues. |
format | Text |
id | pubmed-2977301 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29773012010-12-30 2-Acetamido-2-deoxy-3-O-β-d-galactopyranosyl-d-glucose dihydrate Wada, Masahisa Kobayashi, Kayoko Nishimoto, Mamoru Kitaoka, Motomitsu Noguchi, Keiichi Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(14)H(25)NO(11)·2H(2)O, the primary hydroxyl group connected to the anomeric C atom of the N-acetyl-β-d-glucopyranose residue exhibits positional disorder, with occupancy factors for the α and β anomers of 0.77 and 0.23, respectively. The two torsion angles (Φ and Ψ) and the bridge angle (τ) that describe conformation of the glycosidic linkage between the galactopyranose and glucopyranose rings are Φ = −81.6 (3)°, Ψ = 118.1 (2)° and τ = 115.2 (2)°. Two water molecules stabilize the molecular packing by forming hydrogen bonds with the saccharide residues. International Union of Crystallography 2009-07-04 /pmc/articles/PMC2977301/ /pubmed/21583488 http://dx.doi.org/10.1107/S1600536809024775 Text en © Wada et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Wada, Masahisa Kobayashi, Kayoko Nishimoto, Mamoru Kitaoka, Motomitsu Noguchi, Keiichi 2-Acetamido-2-deoxy-3-O-β-d-galactopyranosyl-d-glucose dihydrate |
title | 2-Acetamido-2-deoxy-3-O-β-d-galactopyranosyl-d-glucose dihydrate |
title_full | 2-Acetamido-2-deoxy-3-O-β-d-galactopyranosyl-d-glucose dihydrate |
title_fullStr | 2-Acetamido-2-deoxy-3-O-β-d-galactopyranosyl-d-glucose dihydrate |
title_full_unstemmed | 2-Acetamido-2-deoxy-3-O-β-d-galactopyranosyl-d-glucose dihydrate |
title_short | 2-Acetamido-2-deoxy-3-O-β-d-galactopyranosyl-d-glucose dihydrate |
title_sort | 2-acetamido-2-deoxy-3-o-β-d-galactopyranosyl-d-glucose dihydrate |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977301/ https://www.ncbi.nlm.nih.gov/pubmed/21583488 http://dx.doi.org/10.1107/S1600536809024775 |
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