Ethyl 5-cyano-4-[2-(2,4-dichloro­phen­oxy)acetamido]-1-phenyl-1H-pyrrole-3-carboxyl­ate

In the title compound, C(22)H(17)Cl(2)N(3)O(4), the pyrrole ring and the 2,4-dichloro­phenyl group form a dihedral angle of 8.14 (13)°; the phenyl ring is twisted with respect to the pyrrole ring, forming a dihedral angle of 60.77 (14)°. The C=O bond length is 1.213 (3) Å, indicating that the mol­ec...

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Detalles Bibliográficos
Autores principales: Xu, Jing, Sheng, Hui, He, Mei, He, Ping
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977304/
https://www.ncbi.nlm.nih.gov/pubmed/21583630
http://dx.doi.org/10.1107/S1600536809027809
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author Xu, Jing
Sheng, Hui
He, Mei
He, Ping
author_facet Xu, Jing
Sheng, Hui
He, Mei
He, Ping
author_sort Xu, Jing
collection PubMed
description In the title compound, C(22)H(17)Cl(2)N(3)O(4), the pyrrole ring and the 2,4-dichloro­phenyl group form a dihedral angle of 8.14 (13)°; the phenyl ring is twisted with respect to the pyrrole ring, forming a dihedral angle of 60.77 (14)°. The C=O bond length is 1.213 (3) Å, indicating that the mol­ecule is in the keto form, associated with a –CONH– group, and the amide group adopts the usual trans conformation. The mol­ecule is stabilized by an intra­molecular N—H⋯O hydrogen-bonding inter­action. In the crystal, the stacked mol­ecules exhibit inter­molecular C—H⋯O and C—H⋯N hydrogen-bonding inter­actions.
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spelling pubmed-29773042010-12-30 Ethyl 5-cyano-4-[2-(2,4-dichloro­phen­oxy)acetamido]-1-phenyl-1H-pyrrole-3-carboxyl­ate Xu, Jing Sheng, Hui He, Mei He, Ping Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(22)H(17)Cl(2)N(3)O(4), the pyrrole ring and the 2,4-dichloro­phenyl group form a dihedral angle of 8.14 (13)°; the phenyl ring is twisted with respect to the pyrrole ring, forming a dihedral angle of 60.77 (14)°. The C=O bond length is 1.213 (3) Å, indicating that the mol­ecule is in the keto form, associated with a –CONH– group, and the amide group adopts the usual trans conformation. The mol­ecule is stabilized by an intra­molecular N—H⋯O hydrogen-bonding inter­action. In the crystal, the stacked mol­ecules exhibit inter­molecular C—H⋯O and C—H⋯N hydrogen-bonding inter­actions. International Union of Crystallography 2009-07-22 /pmc/articles/PMC2977304/ /pubmed/21583630 http://dx.doi.org/10.1107/S1600536809027809 Text en © Xu et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Xu, Jing
Sheng, Hui
He, Mei
He, Ping
Ethyl 5-cyano-4-[2-(2,4-dichloro­phen­oxy)acetamido]-1-phenyl-1H-pyrrole-3-carboxyl­ate
title Ethyl 5-cyano-4-[2-(2,4-dichloro­phen­oxy)acetamido]-1-phenyl-1H-pyrrole-3-carboxyl­ate
title_full Ethyl 5-cyano-4-[2-(2,4-dichloro­phen­oxy)acetamido]-1-phenyl-1H-pyrrole-3-carboxyl­ate
title_fullStr Ethyl 5-cyano-4-[2-(2,4-dichloro­phen­oxy)acetamido]-1-phenyl-1H-pyrrole-3-carboxyl­ate
title_full_unstemmed Ethyl 5-cyano-4-[2-(2,4-dichloro­phen­oxy)acetamido]-1-phenyl-1H-pyrrole-3-carboxyl­ate
title_short Ethyl 5-cyano-4-[2-(2,4-dichloro­phen­oxy)acetamido]-1-phenyl-1H-pyrrole-3-carboxyl­ate
title_sort ethyl 5-cyano-4-[2-(2,4-dichloro­phen­oxy)acetamido]-1-phenyl-1h-pyrrole-3-carboxyl­ate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977304/
https://www.ncbi.nlm.nih.gov/pubmed/21583630
http://dx.doi.org/10.1107/S1600536809027809
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AT hemei ethyl5cyano4224dichlorophenoxyacetamido1phenyl1hpyrrole3carboxylate
AT heping ethyl5cyano4224dichlorophenoxyacetamido1phenyl1hpyrrole3carboxylate

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