Dichloridobis{6-methyl-2-[(trimethyl­silyl)amino]pyridine-κN (1)}cobalt(II)

In the structure of the title compound, [CoCl(2)(C(9)H(16)N(2)Si)(2)], the Co(II) atom is located on an inversion center in a slightly distorted tetra­hedral environment formed by two chloride ions and the pyridine N atoms of two chelating 6-methyl-2-[(trimethyl­silyl)amino]pyridine ligands. The dih...

Descripción completa

Detalles Bibliográficos
Autores principales: Xue, Xiaoyan, Chen, Xia, Tong, Hongbo
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977306/
https://www.ncbi.nlm.nih.gov/pubmed/21583404
http://dx.doi.org/10.1107/S1600536809027937
_version_ 1782191076496375808
author Xue, Xiaoyan
Chen, Xia
Tong, Hongbo
author_facet Xue, Xiaoyan
Chen, Xia
Tong, Hongbo
author_sort Xue, Xiaoyan
collection PubMed
description In the structure of the title compound, [CoCl(2)(C(9)H(16)N(2)Si)(2)], the Co(II) atom is located on an inversion center in a slightly distorted tetra­hedral environment formed by two chloride ions and the pyridine N atoms of two chelating 6-methyl-2-[(trimethyl­silyl)amino]pyridine ligands. The dihedral angle between the planes of the pyridine rings is 80.06 (5)°. Cohesion within the crystal structure is accomplished by N—H⋯Cl hydrogen bonds.
format Text
id pubmed-2977306
institution National Center for Biotechnology Information
language English
publishDate 2009
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29773062010-12-30 Dichloridobis{6-methyl-2-[(trimethyl­silyl)amino]pyridine-κN (1)}cobalt(II) Xue, Xiaoyan Chen, Xia Tong, Hongbo Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the structure of the title compound, [CoCl(2)(C(9)H(16)N(2)Si)(2)], the Co(II) atom is located on an inversion center in a slightly distorted tetra­hedral environment formed by two chloride ions and the pyridine N atoms of two chelating 6-methyl-2-[(trimethyl­silyl)amino]pyridine ligands. The dihedral angle between the planes of the pyridine rings is 80.06 (5)°. Cohesion within the crystal structure is accomplished by N—H⋯Cl hydrogen bonds. International Union of Crystallography 2009-07-22 /pmc/articles/PMC2977306/ /pubmed/21583404 http://dx.doi.org/10.1107/S1600536809027937 Text en © Xue et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Xue, Xiaoyan
Chen, Xia
Tong, Hongbo
Dichloridobis{6-methyl-2-[(trimethyl­silyl)amino]pyridine-κN (1)}cobalt(II)
title Dichloridobis{6-methyl-2-[(trimethyl­silyl)amino]pyridine-κN (1)}cobalt(II)
title_full Dichloridobis{6-methyl-2-[(trimethyl­silyl)amino]pyridine-κN (1)}cobalt(II)
title_fullStr Dichloridobis{6-methyl-2-[(trimethyl­silyl)amino]pyridine-κN (1)}cobalt(II)
title_full_unstemmed Dichloridobis{6-methyl-2-[(trimethyl­silyl)amino]pyridine-κN (1)}cobalt(II)
title_short Dichloridobis{6-methyl-2-[(trimethyl­silyl)amino]pyridine-κN (1)}cobalt(II)
title_sort dichloridobis{6-methyl-2-[(trimethyl­silyl)amino]pyridine-κn (1)}cobalt(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977306/
https://www.ncbi.nlm.nih.gov/pubmed/21583404
http://dx.doi.org/10.1107/S1600536809027937
work_keys_str_mv AT xuexiaoyan dichloridobis6methyl2trimethylsilylaminopyridinekn1cobaltii
AT chenxia dichloridobis6methyl2trimethylsilylaminopyridinekn1cobaltii
AT tonghongbo dichloridobis6methyl2trimethylsilylaminopyridinekn1cobaltii

Ejemplares similares