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Bis(2,3-diamino­pyridinium) succinate trihydrate

In the title salt, 2C(5)H(8)N(3) (+)·C(4)H(4)O(4) (2−)·3H(2)O, the asymmetric unit contains a protonated 2,3-diamino­pyridinium cation, half of a succinate dianion (disposed about a centre of inversion), and one and a half water mol­ecules. One of the water mol­ecules is disordered over two sites wi...

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Autores principales: Fun, Hoong-Kun, Balasubramani, Kasthuri, Yeap, Chin Sing
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977310/
https://www.ncbi.nlm.nih.gov/pubmed/21583553
http://dx.doi.org/10.1107/S1600536809026439
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author Fun, Hoong-Kun
Balasubramani, Kasthuri
Yeap, Chin Sing
author_facet Fun, Hoong-Kun
Balasubramani, Kasthuri
Yeap, Chin Sing
author_sort Fun, Hoong-Kun
collection PubMed
description In the title salt, 2C(5)H(8)N(3) (+)·C(4)H(4)O(4) (2−)·3H(2)O, the asymmetric unit contains a protonated 2,3-diamino­pyridinium cation, half of a succinate dianion (disposed about a centre of inversion), and one and a half water mol­ecules. One of the water mol­ecules is disordered over two sites with occupancies of 0.670 (17) and 0.330 (17). The other water mol­ecule has an occupancy of 0.5 (from refinement). The pyridine N atom of the 2,3-diamino­pyridine mol­ecule is protonated. The protonated N atom and one of the 2-amino H atoms are hydrogen bonded to the succinate anion through a pair of N—H⋯O hydrogen bonds, forming an R (2) (2)(8) ring motif. In the crystal, mol­ecules are consolidated into a three-dimensional network by N—H⋯O and O—H⋯O inter­actions.
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spelling pubmed-29773102010-12-30 Bis(2,3-diamino­pyridinium) succinate trihydrate Fun, Hoong-Kun Balasubramani, Kasthuri Yeap, Chin Sing Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title salt, 2C(5)H(8)N(3) (+)·C(4)H(4)O(4) (2−)·3H(2)O, the asymmetric unit contains a protonated 2,3-diamino­pyridinium cation, half of a succinate dianion (disposed about a centre of inversion), and one and a half water mol­ecules. One of the water mol­ecules is disordered over two sites with occupancies of 0.670 (17) and 0.330 (17). The other water mol­ecule has an occupancy of 0.5 (from refinement). The pyridine N atom of the 2,3-diamino­pyridine mol­ecule is protonated. The protonated N atom and one of the 2-amino H atoms are hydrogen bonded to the succinate anion through a pair of N—H⋯O hydrogen bonds, forming an R (2) (2)(8) ring motif. In the crystal, mol­ecules are consolidated into a three-dimensional network by N—H⋯O and O—H⋯O inter­actions. International Union of Crystallography 2009-07-15 /pmc/articles/PMC2977310/ /pubmed/21583553 http://dx.doi.org/10.1107/S1600536809026439 Text en © Fun et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Fun, Hoong-Kun
Balasubramani, Kasthuri
Yeap, Chin Sing
Bis(2,3-diamino­pyridinium) succinate trihydrate
title Bis(2,3-diamino­pyridinium) succinate trihydrate
title_full Bis(2,3-diamino­pyridinium) succinate trihydrate
title_fullStr Bis(2,3-diamino­pyridinium) succinate trihydrate
title_full_unstemmed Bis(2,3-diamino­pyridinium) succinate trihydrate
title_short Bis(2,3-diamino­pyridinium) succinate trihydrate
title_sort bis(2,3-diamino­pyridinium) succinate trihydrate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977310/
https://www.ncbi.nlm.nih.gov/pubmed/21583553
http://dx.doi.org/10.1107/S1600536809026439
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