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Bis(2,3-diaminopyridinium) succinate trihydrate
In the title salt, 2C(5)H(8)N(3) (+)·C(4)H(4)O(4) (2−)·3H(2)O, the asymmetric unit contains a protonated 2,3-diaminopyridinium cation, half of a succinate dianion (disposed about a centre of inversion), and one and a half water molecules. One of the water molecules is disordered over two sites wi...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977310/ https://www.ncbi.nlm.nih.gov/pubmed/21583553 http://dx.doi.org/10.1107/S1600536809026439 |
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author | Fun, Hoong-Kun Balasubramani, Kasthuri Yeap, Chin Sing |
author_facet | Fun, Hoong-Kun Balasubramani, Kasthuri Yeap, Chin Sing |
author_sort | Fun, Hoong-Kun |
collection | PubMed |
description | In the title salt, 2C(5)H(8)N(3) (+)·C(4)H(4)O(4) (2−)·3H(2)O, the asymmetric unit contains a protonated 2,3-diaminopyridinium cation, half of a succinate dianion (disposed about a centre of inversion), and one and a half water molecules. One of the water molecules is disordered over two sites with occupancies of 0.670 (17) and 0.330 (17). The other water molecule has an occupancy of 0.5 (from refinement). The pyridine N atom of the 2,3-diaminopyridine molecule is protonated. The protonated N atom and one of the 2-amino H atoms are hydrogen bonded to the succinate anion through a pair of N—H⋯O hydrogen bonds, forming an R (2) (2)(8) ring motif. In the crystal, molecules are consolidated into a three-dimensional network by N—H⋯O and O—H⋯O interactions. |
format | Text |
id | pubmed-2977310 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29773102010-12-30 Bis(2,3-diaminopyridinium) succinate trihydrate Fun, Hoong-Kun Balasubramani, Kasthuri Yeap, Chin Sing Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title salt, 2C(5)H(8)N(3) (+)·C(4)H(4)O(4) (2−)·3H(2)O, the asymmetric unit contains a protonated 2,3-diaminopyridinium cation, half of a succinate dianion (disposed about a centre of inversion), and one and a half water molecules. One of the water molecules is disordered over two sites with occupancies of 0.670 (17) and 0.330 (17). The other water molecule has an occupancy of 0.5 (from refinement). The pyridine N atom of the 2,3-diaminopyridine molecule is protonated. The protonated N atom and one of the 2-amino H atoms are hydrogen bonded to the succinate anion through a pair of N—H⋯O hydrogen bonds, forming an R (2) (2)(8) ring motif. In the crystal, molecules are consolidated into a three-dimensional network by N—H⋯O and O—H⋯O interactions. International Union of Crystallography 2009-07-15 /pmc/articles/PMC2977310/ /pubmed/21583553 http://dx.doi.org/10.1107/S1600536809026439 Text en © Fun et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Fun, Hoong-Kun Balasubramani, Kasthuri Yeap, Chin Sing Bis(2,3-diaminopyridinium) succinate trihydrate |
title | Bis(2,3-diaminopyridinium) succinate trihydrate |
title_full | Bis(2,3-diaminopyridinium) succinate trihydrate |
title_fullStr | Bis(2,3-diaminopyridinium) succinate trihydrate |
title_full_unstemmed | Bis(2,3-diaminopyridinium) succinate trihydrate |
title_short | Bis(2,3-diaminopyridinium) succinate trihydrate |
title_sort | bis(2,3-diaminopyridinium) succinate trihydrate |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977310/ https://www.ncbi.nlm.nih.gov/pubmed/21583553 http://dx.doi.org/10.1107/S1600536809026439 |
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