5-Chloro-7-methyl-2-phenyl-3-phenyl­sulfinyl-1-benzofuran

In the title compound, C(21)H(15)ClO(2)S, the O atom and the phenyl group of the phenyl­sulfinyl substituent lie on opposite sides of the plane of the benzofuran fragment; the phenyl ring is almost perpendicular to this plane [82.24 (7)°]. The phenyl ring in the 2-position is rotated out of the benz...

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Detalles Bibliográficos
Autores principales: Choi, Hong Dae, Seo, Pil Ja, Son, Byeng Wha, Lee, Uk
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977311/
https://www.ncbi.nlm.nih.gov/pubmed/21583477
http://dx.doi.org/10.1107/S1600536809024763
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author Choi, Hong Dae
Seo, Pil Ja
Son, Byeng Wha
Lee, Uk
author_facet Choi, Hong Dae
Seo, Pil Ja
Son, Byeng Wha
Lee, Uk
author_sort Choi, Hong Dae
collection PubMed
description In the title compound, C(21)H(15)ClO(2)S, the O atom and the phenyl group of the phenyl­sulfinyl substituent lie on opposite sides of the plane of the benzofuran fragment; the phenyl ring is almost perpendicular to this plane [82.24 (7)°]. The phenyl ring in the 2-position is rotated out of the benzofuran plane, making a dihedral angle of 11.50 (9)°. The crystal structure is stabilized by inter­molecular C—H⋯O and C—H⋯Cl inter­actions. In addition, the stacked mol­ecules exhibit an inter­molecular S⋯O inter­action [3.327 (2) Å] involving the sulfinyl groups.
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spelling pubmed-29773112010-12-30 5-Chloro-7-methyl-2-phenyl-3-phenyl­sulfinyl-1-benzofuran Choi, Hong Dae Seo, Pil Ja Son, Byeng Wha Lee, Uk Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(21)H(15)ClO(2)S, the O atom and the phenyl group of the phenyl­sulfinyl substituent lie on opposite sides of the plane of the benzofuran fragment; the phenyl ring is almost perpendicular to this plane [82.24 (7)°]. The phenyl ring in the 2-position is rotated out of the benzofuran plane, making a dihedral angle of 11.50 (9)°. The crystal structure is stabilized by inter­molecular C—H⋯O and C—H⋯Cl inter­actions. In addition, the stacked mol­ecules exhibit an inter­molecular S⋯O inter­action [3.327 (2) Å] involving the sulfinyl groups. International Union of Crystallography 2009-07-04 /pmc/articles/PMC2977311/ /pubmed/21583477 http://dx.doi.org/10.1107/S1600536809024763 Text en © Choi et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Choi, Hong Dae
Seo, Pil Ja
Son, Byeng Wha
Lee, Uk
5-Chloro-7-methyl-2-phenyl-3-phenyl­sulfinyl-1-benzofuran
title 5-Chloro-7-methyl-2-phenyl-3-phenyl­sulfinyl-1-benzofuran
title_full 5-Chloro-7-methyl-2-phenyl-3-phenyl­sulfinyl-1-benzofuran
title_fullStr 5-Chloro-7-methyl-2-phenyl-3-phenyl­sulfinyl-1-benzofuran
title_full_unstemmed 5-Chloro-7-methyl-2-phenyl-3-phenyl­sulfinyl-1-benzofuran
title_short 5-Chloro-7-methyl-2-phenyl-3-phenyl­sulfinyl-1-benzofuran
title_sort 5-chloro-7-methyl-2-phenyl-3-phenyl­sulfinyl-1-benzofuran
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977311/
https://www.ncbi.nlm.nih.gov/pubmed/21583477
http://dx.doi.org/10.1107/S1600536809024763
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AT seopilja 5chloro7methyl2phenyl3phenylsulfinyl1benzofuran
AT sonbyengwha 5chloro7methyl2phenyl3phenylsulfinyl1benzofuran
AT leeuk 5chloro7methyl2phenyl3phenylsulfinyl1benzofuran

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