2,3-Bis(3-fluoro­phen­yl)tetra­zolium-5-thiol­ate

The zwitterionic title compound, C(13)H(8)F(2)N(4)S, is situated on a twofold rotation axis running along the C—S [1.691 (2) Å] single bond. The phenyl­ene ring is twisted out of the tetra­zolium plane by 42.18 (7)°. Relatively short distances [3.7572 (9) and 4.0625 (6) Å] between the centroids of t...

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Detalles Bibliográficos
Autores principales: von Eschwege, Karel G., Muller, Alfred
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977314/
https://www.ncbi.nlm.nih.gov/pubmed/21583560
http://dx.doi.org/10.1107/S1600536809026683
Descripción
Sumario:The zwitterionic title compound, C(13)H(8)F(2)N(4)S, is situated on a twofold rotation axis running along the C—S [1.691 (2) Å] single bond. The phenyl­ene ring is twisted out of the tetra­zolium plane by 42.18 (7)°. Relatively short distances [3.7572 (9) and 4.0625 (6) Å] between the centroids of the phenyl­ene and tetra­zolium rings of neighbouring mol­ecules suggest π–π inter­actions. The crystal under investigation was a non-merohedral twin, with a 33% twin component.

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