Stemofoline ethyl acetate solvate

Crystals of the title compound, C(22)H(29)NO(5)·C(4)H(8)O(2), {[systematic name: (2R,3R,5R,5aS,6R,8aR,9S)-(5Z)-5-[3-butyl­tetra­hydro-6-methyl-2,5-methano-4,3,8a-[1]propan­yl[3]yl­idene­furo[3,2-f][1,4]oxazepin-7(5H)-yl­idene]-4-meth­oxy-3-methyl­furan-2(5H)-one ethyl acetate solvate} were isolated...

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Detalles Bibliográficos
Autores principales: Mungkornasawakul, Pitchaya, Pyne, Stephen G., Ung, Alison T., Jatisatienr, Araya, Willis, Anthony C.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977317/
https://www.ncbi.nlm.nih.gov/pubmed/21583572
http://dx.doi.org/10.1107/S1600536809026889
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author Mungkornasawakul, Pitchaya
Pyne, Stephen G.
Ung, Alison T.
Jatisatienr, Araya
Willis, Anthony C.
author_facet Mungkornasawakul, Pitchaya
Pyne, Stephen G.
Ung, Alison T.
Jatisatienr, Araya
Willis, Anthony C.
author_sort Mungkornasawakul, Pitchaya
collection PubMed
description Crystals of the title compound, C(22)H(29)NO(5)·C(4)H(8)O(2), {[systematic name: (2R,3R,5R,5aS,6R,8aR,9S)-(5Z)-5-[3-butyl­tetra­hydro-6-methyl-2,5-methano-4,3,8a-[1]propan­yl[3]yl­idene­furo[3,2-f][1,4]oxazepin-7(5H)-yl­idene]-4-meth­oxy-3-methyl­furan-2(5H)-one ethyl acetate solvate} were isolated from the root extracts of Stemona aphylla (Stemonaceae). The structure closely resembles those of stemofoline derivatives which have previously been reported. Inter­molecular contacts are observed between some C-bonded H atoms and nearby O atoms, perhaps indicating weak inter­actions which could influence the packing of species within the unit cell.
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spelling pubmed-29773172010-12-30 Stemofoline ethyl acetate solvate Mungkornasawakul, Pitchaya Pyne, Stephen G. Ung, Alison T. Jatisatienr, Araya Willis, Anthony C. Acta Crystallogr Sect E Struct Rep Online Organic Papers Crystals of the title compound, C(22)H(29)NO(5)·C(4)H(8)O(2), {[systematic name: (2R,3R,5R,5aS,6R,8aR,9S)-(5Z)-5-[3-butyl­tetra­hydro-6-methyl-2,5-methano-4,3,8a-[1]propan­yl[3]yl­idene­furo[3,2-f][1,4]oxazepin-7(5H)-yl­idene]-4-meth­oxy-3-methyl­furan-2(5H)-one ethyl acetate solvate} were isolated from the root extracts of Stemona aphylla (Stemonaceae). The structure closely resembles those of stemofoline derivatives which have previously been reported. Inter­molecular contacts are observed between some C-bonded H atoms and nearby O atoms, perhaps indicating weak inter­actions which could influence the packing of species within the unit cell. International Union of Crystallography 2009-07-18 /pmc/articles/PMC2977317/ /pubmed/21583572 http://dx.doi.org/10.1107/S1600536809026889 Text en © Mungkornasawakul et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Mungkornasawakul, Pitchaya
Pyne, Stephen G.
Ung, Alison T.
Jatisatienr, Araya
Willis, Anthony C.
Stemofoline ethyl acetate solvate
title Stemofoline ethyl acetate solvate
title_full Stemofoline ethyl acetate solvate
title_fullStr Stemofoline ethyl acetate solvate
title_full_unstemmed Stemofoline ethyl acetate solvate
title_short Stemofoline ethyl acetate solvate
title_sort stemofoline ethyl acetate solvate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977317/
https://www.ncbi.nlm.nih.gov/pubmed/21583572
http://dx.doi.org/10.1107/S1600536809026889
work_keys_str_mv AT mungkornasawakulpitchaya stemofolineethylacetatesolvate
AT pynestepheng stemofolineethylacetatesolvate
AT ungalisont stemofolineethylacetatesolvate
AT jatisatienraraya stemofolineethylacetatesolvate
AT willisanthonyc stemofolineethylacetatesolvate

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