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Aquachloridobis[5-(2-pyridyl)-1H-tetrazolato-κN (1)]iron(III)
The title compound, [Fe(C(6)H(4)N(5))(2)Cl(H(2)O)], was synthesized by hydrothermal reaction of FeCl(3) with 2-(1H-tetrazol-5-yl)pyridine. The iron(III) metal centre exhibits a distorted octahedral coordination geometry provided by four N atoms from two bidentate organic ligands, one water O atom...
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977327/ https://www.ncbi.nlm.nih.gov/pubmed/21583329 http://dx.doi.org/10.1107/S160053680902443X |
Sumario: | The title compound, [Fe(C(6)H(4)N(5))(2)Cl(H(2)O)], was synthesized by hydrothermal reaction of FeCl(3) with 2-(1H-tetrazol-5-yl)pyridine. The iron(III) metal centre exhibits a distorted octahedral coordination geometry provided by four N atoms from two bidentate organic ligands, one water O atom and one chloride anion. The pyridine and tetrazole rings are nearly coplanar [dihedral angles = 4.32 (15) and 5.04 (14)°]. In the crystal structure, intermolecular O—H⋯N hydrogen bonds link the complex molecules into a two-dimensional network parallel to (100). |
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