Aqua­chloridobis[5-(2-pyrid­yl)-1H-tetra­zolato-κN (1)]iron(III)

The title compound, [Fe(C(6)H(4)N(5))(2)Cl(H(2)O)], was synthesized by hydro­thermal reaction of FeCl(3) with 2-(1H-tetra­zol-5-yl)pyridine. The iron(III) metal centre exhibits a distorted octa­hedral coordination geometry provided by four N atoms from two bidentate organic ligands, one water O atom...

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Detalles Bibliográficos
Autor principal: Wang, Bo
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977327/
https://www.ncbi.nlm.nih.gov/pubmed/21583329
http://dx.doi.org/10.1107/S160053680902443X
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author Wang, Bo
author_facet Wang, Bo
author_sort Wang, Bo
collection PubMed
description The title compound, [Fe(C(6)H(4)N(5))(2)Cl(H(2)O)], was synthesized by hydro­thermal reaction of FeCl(3) with 2-(1H-tetra­zol-5-yl)pyridine. The iron(III) metal centre exhibits a distorted octa­hedral coordination geometry provided by four N atoms from two bidentate organic ligands, one water O atom and one chloride anion. The pyridine and tetra­zole rings are nearly coplanar [dihedral angles = 4.32 (15) and 5.04 (14)°]. In the crystal structure, inter­molecular O—H⋯N hydrogen bonds link the complex mol­ecules into a two-dimensional network parallel to (100).
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spelling pubmed-29773272010-12-30 Aqua­chloridobis[5-(2-pyrid­yl)-1H-tetra­zolato-κN (1)]iron(III) Wang, Bo Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Fe(C(6)H(4)N(5))(2)Cl(H(2)O)], was synthesized by hydro­thermal reaction of FeCl(3) with 2-(1H-tetra­zol-5-yl)pyridine. The iron(III) metal centre exhibits a distorted octa­hedral coordination geometry provided by four N atoms from two bidentate organic ligands, one water O atom and one chloride anion. The pyridine and tetra­zole rings are nearly coplanar [dihedral angles = 4.32 (15) and 5.04 (14)°]. In the crystal structure, inter­molecular O—H⋯N hydrogen bonds link the complex mol­ecules into a two-dimensional network parallel to (100). International Union of Crystallography 2009-07-01 /pmc/articles/PMC2977327/ /pubmed/21583329 http://dx.doi.org/10.1107/S160053680902443X Text en © Bo Wang 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wang, Bo
Aqua­chloridobis[5-(2-pyrid­yl)-1H-tetra­zolato-κN (1)]iron(III)
title Aqua­chloridobis[5-(2-pyrid­yl)-1H-tetra­zolato-κN (1)]iron(III)
title_full Aqua­chloridobis[5-(2-pyrid­yl)-1H-tetra­zolato-κN (1)]iron(III)
title_fullStr Aqua­chloridobis[5-(2-pyrid­yl)-1H-tetra­zolato-κN (1)]iron(III)
title_full_unstemmed Aqua­chloridobis[5-(2-pyrid­yl)-1H-tetra­zolato-κN (1)]iron(III)
title_short Aqua­chloridobis[5-(2-pyrid­yl)-1H-tetra­zolato-κN (1)]iron(III)
title_sort aqua­chloridobis[5-(2-pyrid­yl)-1h-tetra­zolato-κn (1)]iron(iii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977327/
https://www.ncbi.nlm.nih.gov/pubmed/21583329
http://dx.doi.org/10.1107/S160053680902443X
work_keys_str_mv AT wangbo aquachloridobis52pyridyl1htetrazolatokn1ironiii

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