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Di-μ-sulfato-κ(4) O:O′-bis[diaqua(1H-imidazo[4,5-f][1,10]phenanthroline-κ(2) N (7),N (9))cobalt(II)] dihydrate
In the centrosymmetric dinuclear title compound, [Co(2)(SO(4))(2)(C(13)H(8)N(4))(2)(H(2)O)(4)]·2H(2)O, the Co(II) atom is coordinated by two N atoms from two 1H-imidazo[4,5-f][1,10]phenanthroline ligands, two O atoms from two sulfate anions and two O atoms from water molecules in a distorted octa...
| Autores principales: | , , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2009
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977338/ https://www.ncbi.nlm.nih.gov/pubmed/21583315 http://dx.doi.org/10.1107/S1600536809024295 |
| Sumario: | In the centrosymmetric dinuclear title compound, [Co(2)(SO(4))(2)(C(13)H(8)N(4))(2)(H(2)O)(4)]·2H(2)O, the Co(II) atom is coordinated by two N atoms from two 1H-imidazo[4,5-f][1,10]phenanthroline ligands, two O atoms from two sulfate anions and two O atoms from water molecules in a distorted octahedral geometry. The Co⋯Co separation is 5.1167 (7) Å. The coordinated and uncoordinated water molecules engage in N—H⋯O and O—H⋯O hydrogen-bonding interactions. |
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