Di-μ-sulfato-κ(4) O:O′-bis­[diaqua­(1H-imidazo[4,5-f][1,10]phenanthroline-κ(2) N (7),N (9))cobalt(II)] dihydrate

In the centrosymmetric dinuclear title compound, [Co(2)(SO(4))(2)(C(13)H(8)N(4))(2)(H(2)O)(4)]·2H(2)O, the Co(II) atom is coord­in­ated by two N atoms from two 1H-imidazo[4,5-f][1,10]phenanthroline ligands, two O atoms from two sulfate anions and two O atoms from water mol­ecules in a distorted octa...

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Detalles Bibliográficos
Autores principales: Gong, Yun, Zhou, Yuchao, Li, Jinghua, Wu, Xiaoxia, Qin, Jianbo
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977338/
https://www.ncbi.nlm.nih.gov/pubmed/21583315
http://dx.doi.org/10.1107/S1600536809024295
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author Gong, Yun
Zhou, Yuchao
Li, Jinghua
Wu, Xiaoxia
Qin, Jianbo
author_facet Gong, Yun
Zhou, Yuchao
Li, Jinghua
Wu, Xiaoxia
Qin, Jianbo
author_sort Gong, Yun
collection PubMed
description In the centrosymmetric dinuclear title compound, [Co(2)(SO(4))(2)(C(13)H(8)N(4))(2)(H(2)O)(4)]·2H(2)O, the Co(II) atom is coord­in­ated by two N atoms from two 1H-imidazo[4,5-f][1,10]phenanthroline ligands, two O atoms from two sulfate anions and two O atoms from water mol­ecules in a distorted octa­hedral geometry. The Co⋯Co separation is 5.1167 (7) Å. The coordinated and uncoordinated water mol­ecules engage in N—H⋯O and O—H⋯O hydrogen-bonding inter­actions.
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spelling pubmed-29773382010-12-30 Di-μ-sulfato-κ(4) O:O′-bis­[diaqua­(1H-imidazo[4,5-f][1,10]phenanthroline-κ(2) N (7),N (9))cobalt(II)] dihydrate Gong, Yun Zhou, Yuchao Li, Jinghua Wu, Xiaoxia Qin, Jianbo Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the centrosymmetric dinuclear title compound, [Co(2)(SO(4))(2)(C(13)H(8)N(4))(2)(H(2)O)(4)]·2H(2)O, the Co(II) atom is coord­in­ated by two N atoms from two 1H-imidazo[4,5-f][1,10]phenanthroline ligands, two O atoms from two sulfate anions and two O atoms from water mol­ecules in a distorted octa­hedral geometry. The Co⋯Co separation is 5.1167 (7) Å. The coordinated and uncoordinated water mol­ecules engage in N—H⋯O and O—H⋯O hydrogen-bonding inter­actions. International Union of Crystallography 2009-07-01 /pmc/articles/PMC2977338/ /pubmed/21583315 http://dx.doi.org/10.1107/S1600536809024295 Text en © Gong et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Gong, Yun
Zhou, Yuchao
Li, Jinghua
Wu, Xiaoxia
Qin, Jianbo
Di-μ-sulfato-κ(4) O:O′-bis­[diaqua­(1H-imidazo[4,5-f][1,10]phenanthroline-κ(2) N (7),N (9))cobalt(II)] dihydrate
title Di-μ-sulfato-κ(4) O:O′-bis­[diaqua­(1H-imidazo[4,5-f][1,10]phenanthroline-κ(2) N (7),N (9))cobalt(II)] dihydrate
title_full Di-μ-sulfato-κ(4) O:O′-bis­[diaqua­(1H-imidazo[4,5-f][1,10]phenanthroline-κ(2) N (7),N (9))cobalt(II)] dihydrate
title_fullStr Di-μ-sulfato-κ(4) O:O′-bis­[diaqua­(1H-imidazo[4,5-f][1,10]phenanthroline-κ(2) N (7),N (9))cobalt(II)] dihydrate
title_full_unstemmed Di-μ-sulfato-κ(4) O:O′-bis­[diaqua­(1H-imidazo[4,5-f][1,10]phenanthroline-κ(2) N (7),N (9))cobalt(II)] dihydrate
title_short Di-μ-sulfato-κ(4) O:O′-bis­[diaqua­(1H-imidazo[4,5-f][1,10]phenanthroline-κ(2) N (7),N (9))cobalt(II)] dihydrate
title_sort di-μ-sulfato-κ(4) o:o′-bis­[diaqua­(1h-imidazo[4,5-f][1,10]phenanthroline-κ(2) n (7),n (9))cobalt(ii)] dihydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977338/
https://www.ncbi.nlm.nih.gov/pubmed/21583315
http://dx.doi.org/10.1107/S1600536809024295
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