3-(1-Adamantylamino)-3-methyl-1-phenyl­quinoline-2,4(1H,3H)-dione

The structure of the title compound, C(26)H(28)N(2)O(2), contains essentially planar quinoline and benzene rings, the maximum deviations from the best plane being 0.086 (2) and 0.0056 (19) Å, respectively; the dihedral angle between the rings is 82.87 (4)°. The adamantane cage consists of three fuse...

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Detalles Bibliográficos
Autores principales: Mahmoodi, Niusha, Nečas, Marek, Vícha, Robert
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977340/
https://www.ncbi.nlm.nih.gov/pubmed/21583562
http://dx.doi.org/10.1107/S1600536809026464
Descripción
Sumario:The structure of the title compound, C(26)H(28)N(2)O(2), contains essentially planar quinoline and benzene rings, the maximum deviations from the best plane being 0.086 (2) and 0.0056 (19) Å, respectively; the dihedral angle between the rings is 82.87 (4)°. The adamantane cage consists of three fused cyclo­hexane rings in classical chair conformations, with C—C—C angles in the range 107.85 (15)–111.35 (15)°. Enanti­omers are linked alternately into chains along the c axis via short N—H⋯O inter­actions and further C–H⋯π inter­actions stabilize pairs of enanti­omers, forming a two-dimensional network.

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