3-(1-Adamantylamino)-3-methyl-1-phenyl­quinoline-2,4(1H,3H)-dione

The structure of the title compound, C(26)H(28)N(2)O(2), contains essentially planar quinoline and benzene rings, the maximum deviations from the best plane being 0.086 (2) and 0.0056 (19) Å, respectively; the dihedral angle between the rings is 82.87 (4)°. The adamantane cage consists of three fuse...

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Detalles Bibliográficos
Autores principales: Mahmoodi, Niusha, Nečas, Marek, Vícha, Robert
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977340/
https://www.ncbi.nlm.nih.gov/pubmed/21583562
http://dx.doi.org/10.1107/S1600536809026464
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author Mahmoodi, Niusha
Nečas, Marek
Vícha, Robert
author_facet Mahmoodi, Niusha
Nečas, Marek
Vícha, Robert
author_sort Mahmoodi, Niusha
collection PubMed
description The structure of the title compound, C(26)H(28)N(2)O(2), contains essentially planar quinoline and benzene rings, the maximum deviations from the best plane being 0.086 (2) and 0.0056 (19) Å, respectively; the dihedral angle between the rings is 82.87 (4)°. The adamantane cage consists of three fused cyclo­hexane rings in classical chair conformations, with C—C—C angles in the range 107.85 (15)–111.35 (15)°. Enanti­omers are linked alternately into chains along the c axis via short N—H⋯O inter­actions and further C–H⋯π inter­actions stabilize pairs of enanti­omers, forming a two-dimensional network.
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spelling pubmed-29773402010-12-30 3-(1-Adamantylamino)-3-methyl-1-phenyl­quinoline-2,4(1H,3H)-dione Mahmoodi, Niusha Nečas, Marek Vícha, Robert Acta Crystallogr Sect E Struct Rep Online Organic Papers The structure of the title compound, C(26)H(28)N(2)O(2), contains essentially planar quinoline and benzene rings, the maximum deviations from the best plane being 0.086 (2) and 0.0056 (19) Å, respectively; the dihedral angle between the rings is 82.87 (4)°. The adamantane cage consists of three fused cyclo­hexane rings in classical chair conformations, with C—C—C angles in the range 107.85 (15)–111.35 (15)°. Enanti­omers are linked alternately into chains along the c axis via short N—H⋯O inter­actions and further C–H⋯π inter­actions stabilize pairs of enanti­omers, forming a two-dimensional network. International Union of Crystallography 2009-07-15 /pmc/articles/PMC2977340/ /pubmed/21583562 http://dx.doi.org/10.1107/S1600536809026464 Text en © Mahmoodi et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Mahmoodi, Niusha
Nečas, Marek
Vícha, Robert
3-(1-Adamantylamino)-3-methyl-1-phenyl­quinoline-2,4(1H,3H)-dione
title 3-(1-Adamantylamino)-3-methyl-1-phenyl­quinoline-2,4(1H,3H)-dione
title_full 3-(1-Adamantylamino)-3-methyl-1-phenyl­quinoline-2,4(1H,3H)-dione
title_fullStr 3-(1-Adamantylamino)-3-methyl-1-phenyl­quinoline-2,4(1H,3H)-dione
title_full_unstemmed 3-(1-Adamantylamino)-3-methyl-1-phenyl­quinoline-2,4(1H,3H)-dione
title_short 3-(1-Adamantylamino)-3-methyl-1-phenyl­quinoline-2,4(1H,3H)-dione
title_sort 3-(1-adamantylamino)-3-methyl-1-phenyl­quinoline-2,4(1h,3h)-dione
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977340/
https://www.ncbi.nlm.nih.gov/pubmed/21583562
http://dx.doi.org/10.1107/S1600536809026464
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